Bacteria existing on the surfaces of various materials can be both a source of infection and an obstacle to the proper functioning of structures. Increased resistance to colonization by microorganisms can be obtained by applying antibacterial coatings. This paper describes the influence of surface wettability and amount of antibacterial additive (Zn) on bacteria settlement on modified SiO2-based coatings. The coatings were made by sol-gel method. The sols were prepared on the basis of tetraethoxysilane (TEOS), modified with methyltrimethoxysilane (MTMS), hexamethyldisilazane (HMDS) and the addition of zinc nitrate or zinc acetate. Roughness and surface wettability tests, as well as study of the chemical structure of the coatings were carried out. The antibacterial properties of the coatings were checked by examining their susceptibility to colonization by Escherichia coli. It was found that the addition of zinc compound reduced the susceptibility to colonization by E. coli, while in the studied range, roughness and hydrophobicity did not affect the level of bacteria adhesion to the coatings.
In this work, Al2O3 + graphene coatings were prepared using the sol–gel method. The aim of the study was preliminary determination of the influence of size and amount of graphene nanoplatelets on morphology, chemical structure, and basic tribological properties of Al2O3 + graphene composite coatings. Two types of reduced graphene oxide (rGO) nanoplatelets with different lateral size and thickness were used to prepare the coatings. To characterize them, scanning electron microscope (SEM), glow discharged optical emission spectrometer (GDOES), Fourier-transform infrared (FTIR), reflectance spectrometer, and ball-on-disk tribological tests were used. It was found that the presence of graphene in the Al2O3 + graphene coatings did not fundamentally change the chemical transformation of ceramic Al2O3 matrix. Morphology examinations of coatings containing larger graphene nanoplatelets revealed a tendency to their parallel arrangement in relation to the coated surface. The tribological properties of Al2O3 + graphene coatings turned out to be strongly dependent on the size of graphene nanoplatelets as well as on the heat treatment temperature. The friction coefficient as low as 0.11 and good durability were obtained for the Al2O3 + graphene coating with larger nanoplatelets and heat-treated at 500 °C. The results of conducted research indicate the potential use of Al2O3 + graphene composite coatings prepared by the sol–gel method as low-friction ceramic coatings.
1 October 2013 in Journal of the European Ceramic Society