In recent years, it has been shown that emotions influence what we learn and retain, and second-language learning is no exception to this phenomenon. Currently, a variety of mobile learning applications offer content for language learners, and a wide range of languages are presented. The analysis of emotional data in learning environments has been implemented through various methods, such as the collection of vital signs. This is where brain–computer interfaces (BCIs) play an important role in capturing emotional metrics from brain activity. Accordingly, this paper presents the Emotional Data L2 Interaction (EDaLI) dataset for emotional analysis based on the collection of emotions, such as engagement, stress, excitement, interest, relaxation, and focus, through Emotiv Insight, during the interaction of 19 participants with 4 initial lessons in Portuguese as a second-language, through the Babbel application. A preliminary visualization approach is proposed from the generated dataset. In accordance with this, it is concluded that visualization techniques can clearly be applied to EDaLI to show the emotional behavior exhibited by the participants during their interactions. Additionally, the spectrum of algorithms to be applied is open and includes possibilities such as the use of clustering techniques for time series of variable lengths.