Uthayaraj Siva

Mr. Uthayaraj Siva

M.Phil. candidate

Research Focus & Metrics

Academic Career Length

8Years (2019-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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26 June 2019 in Materials
Verified
Journal Article
Open access
PDF file
USUthayaraj Siva
Uthayaraj Siva
DKD. G. B. C. Karunarathne
D. G. B. C. Karunarathne
GKG. R. A. Kumara
G. R. A. Kumara
TMThanihaichelvan Murugathas
Thanihaichelvan Murugathas
Shivatharsiny ShivatharsinyShivatharsiny Shivatharsiny
Shivatharsiny Shivatharsiny
Dhayalan VelauthapillaiDhayalan Velauthapillai
Dhayalan Velauthapillai
This study focuses on employing cuprous iodide (CuI) as a hole-transporting material (HTM) in fabricating highly efficient perovskite solar cells (PSCs). The PSCs were made in air with either CuI or 2,2′,7,7′-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene (spiro-OMeTAD) as HTMs. A simple and novel pressing method was employed for incorporating CuI powder layer between perovskite layer and Pt top-contact to fabricate devices with CuI, while spiro-OMeTAD was spin-coated between perovskite layer and thermally evaporated Au top-contact to fabricate devices with spiro-OMeTAD. Under illuminations of 100 mW/cm2 with an air mass (AM) 1.5 filter in air, the average short-circuit current density (JSC) of the CuI devices was over 24 mA/cm2, which is marginally higher than that of spiro-OMeTAD devices. Higher JSC of the CuI devices can be attributed to high hole-mobility of CuI that minimizes the electron-hole recombination. However, the average power conversion efficiency (PCE) of the CuI devices were lower than that of spiro-OMeTAD devices due to slightly lower open-circuit voltage (VOC) and fill factor (FF). This is probably due to surface roughness of CuI powder. However, optimized devices with solvent-free powder pressed CuI as HTM show a promising efficiency of over 8.0 % under illuminations of 1 sun (100 mW/cm2) with an air mass 1.5 filter in air, which is the highest among the reported efficiency values for PSCs fabricated in an open environment with CuI as HTM.