Ag-exchanged NaY zeolite (Ag-NaZ) particles were prepared by ion exchange and introduced to a polyvinyl alcohol (PVA) membrane cross-linked with polyacrylic acid (PAA) for the pervaporation dehydration of an isopropanol (IPA) aqueous mixture. The Ag-exchanged NaY zeolite particles were characterized by FE-SEM, EDS, BET, and XRD studies. The prepared Ag-NaZ-loaded PVA/PAA composite membrane was characterized by FE-SEM, XRD, a swelling study, and contact angle measurements. Pervaporation characteristics were investigated in terms of Ag-NaZ concentrations within PVA/PAA membranes using diverse feed solution conditions. The preferential sorption of IPA/water mixtures for Ag-NaZ-introduced membranes were also determined by calculating the apparent activation energies of IPA and water permeation, respectively. As a result, flux and selectivity increased with the Ag-NaZ concentration to 5 wt% in the membrane. Optimum pervaporation performance was observed in a 5 wt% Ag-NaZ-incorporated membrane with a flux equal to 0.084 kg m⁻² h⁻¹ and a separation factor of 2717.9 at 40 °C from an 80 wt% IPA aqueous feed solution.

In order to find an alternative for classical distillation in the recovery of ECH/IPA from azeotropic ECH/IPA/water (50/30/20 w/w, %) mixtures, a pervaporation process has been applied. Membranes from the crosslinking of poly(vinyl alcohol)/poly(vinyl amine) (PVA/PVAm) were prepared, and then the membrane stability and pervaporation efficiency of the crosslinked PVA/PVAm membranes were studied for highly reactive ECH systems containing a ternary feed mixture. From the Fourier-transform infrared (FT-IR) spectroscopy analysis, it was observed that all of the membranes were chemically stable for 15 days of immersion in a 50 : 30 : 20 ECH/IPA/water (w/w, %) feed mixture at 60 °C. The degree of membrane swelling increased with increasing PVAm content in the membrane composition, water content in the feed composition, and feed temperature, which was attributed to the increase in the number of hydrophilic sites in the membrane. The field-emission scanning electron microscopy (FE-SEM) study revealed that higher PVAm content membranes (PVAm1.0 and PVAm1.5) show polymer phase extraction in ECH/IPA/water (50 : 30 : 20) (w/w, %) at 60 °C in long-term stability tests. The pervaporation dehydration characteristics for all of the membranes with the feed comprising an ECH/IPA/water (50 : 30 : 20 by weight) azeotropic mixture at 30 °C were examined and excellent pervaporation dehydration efficiency was found. Quantitatively, the flux increased from 0.025 to 0.32 kg (m² h)⁻¹ and the separation factor decreased from 1908 to 60 with increasing PVAm content in the blended membrane.