The attachment strategy based on catecholic chemistry has been arousing renewed interest since the work on polymerized catecholic amine (polydopamine) (Messersmith et al., Science, 2007, 318, 426) was published. Catechols and their derived compounds can self-assemble on various inorganic and organic materials, including noble metals, metals, metal oxides, mica, silica, ceramics and even polymers. It opens a new route to the modification of various substrates and the preparation of functional composite materials by simple chemistry. However, there is still not a full review so far about the attachment chemistry despite the dramatically increasing number of publications. This critical review describes the state-of-the-art research in the area: the design and synthesis of catecholic molecules, their adsorption mechanisms and the stability of assemblies in solution, and their applications etc. Some perspectives on future development are raised (195 references).

This tutorial review outlines current state of the art research on ionic liquid lubricants. Ionic liquids (ILs) were first reported as very promising high-performance lubricants in 2001 and have attracted considerable attention in the field of tribology since then because of their remarkable lubrication and anti-wear capabilities as compared with lubrication oils in general use; in recent times we have seen dramatically increased interest in the topic. The review starts with a brief introduction to ILs and fluid lubrication, and then discusses in more detail the tribological properties of IL lubricants, either as lubrication oils, additives or thin films. As well as lubrication mechanisms, some current problems and potential solutions are tentatively discussed.

Ionic liquids (ILs) have emerged as potential lubricants in 2001. Subsequently, there has been tremendous research interest in ILs from the tribology society since their discovery as novel synthetic lubricating materials. This also expands the research area of ILs. Consistent with the requirement of searching for alternative and eco-friendly lubricants, IL lubrication will experience further development in the coming years. Herein, we review the research progress of IL lubricants. Generally, the tribological properties of IL lubricants as lubricating oils, additives and thin films are reviewed in detail and their lubrication mechanisms discussed. Considering their actual applications, the flexible design of ILs allows the synthesis of task-specific and tribologically interesting ILs to overcome the drawbacks of the application of ILs, such as high cost, poor compatibility with traditional oils, thermal oxidization and corrosion. Nowadays, increasing research is focused on halogen-free ILs, green ILs, synthesis-free ILs and functional ILs. In addition to their macroscopic properties, the nanoscopic performance of ILs on a small scale and in small gaps is also important in revealing their tribological mechanisms. It has been shown that when sliding surfaces are compressed, in comparison with a less polar molecular lubricant, ion pairs resist “squeeze out” due to the strong interaction between the ions of ILs and oppositely charged surfaces, resulting in a film that remains in place at higher shear forces. Thus, the lubricity of ILs can be externally controlled in situ by applying electric potentials. In summary, ILs demonstrate sufficient design versatility as a type of model lubricant for meeting the requirements of mechanical engineering. Accordingly, their perspectives and future development are discussed in this review.

The design of smart surfaces with switchable adhesive properties in a wet environment has remained a challenge in adhesion science and materials engineering. Despite intense demands in various industrial applications and exciting progress in mimicking the remarkable wet adhesion through the delicate control of catechol chemistry, polyelectrolyte complex, and supramolecular architectures, the full recapitulation of nature’s dynamic function is limited. Here, we show a facile approach to synthesize bioinspired adhesive, which entails the reversible, tunable, and fast regulation of the wet adhesion on diverse surfaces. The smart wet adhesive takes advantage of the host–guest molecular interaction and the adhesive nature of catechol chemistry, as well as the responsive polymer, allowing for screening and activation of the interfacial interaction simply by a local temperature trigger in an on-demand manner. Our work opens up an avenue for the rational design of bioinspired adhesives with performances even beyond nature.