Significant attention has been given during the last few years to overcome technological and material barriers in order to develop organic photovoltaic devices (OPVs) with comparable cost efficiency similar to the inorganic photovoltaics (PVs) and to make them commercially viable. To take advantage of the low cost for such devices, major improvements are necessary which include: an efficiency of around 10%, high stability from degradation under real-world conditions, novel optically active materials, and development of novel fabrication approaches. In order to meet such stringent requirements, the research and development in OPVs need to improve upon the short diffusion length of excitons, which is one of the factors that are responsible for their low power conversion efficiency. This review discusses some of the most significant technological developments that were presented in the literature and helped improve photovoltaic performance, such as tandem architectures, plasmonics, and use of graphitic nanostructural materials, among others. Tandem organic solar cells with embedded plasmonics are a promising approach to further increase the power conversion efficiency of organic solar cells, by harvesting complementary spectral regions with high quantum efficiencies. Polymeric nanocomposites incorporating graphitic nanostructures were extensively investigated for the next generation of efficient and low-cost solar cells, since such nanomaterials show excellent electrical and mechanical properties, excellent carrier transport capabilities, and provide an efficient pathway to the dissociated charge carriers.
Nanotechnology has been extensively explored for cancer diagnostics. However, the specificity of current methods to identify simultaneously several cancer biomarkers is limited due to color overlapping of bio-conjugated nanoparticles. Here, we present a technique to increase both the molecular and spectral specificity of cancer diagnosis by using tunable silver-gold nanorods with narrow surface-enhanced Raman scattering (SERS) and high photothermal contrast. The silver-gold nanorods were functionalized with four Raman-active molecules and four antibodies specific to breast cancer markers and with leukocyte-specific CD45 marker. More than two orders of magnitude of SERS signal enhancement was observed from these hybrid nanosystems compared to conventional gold nanorods. Using an antibody rainbow cocktail, we demonstrated highly specific detection of single breast cancer cells in unprocessed human blood. By integrating multiplex targeting, multicolor coding, and multimodal detection, our approach has the potential to improve multispectral imaging of individual tumor cells in complex biological environments.