Fluorescent carbon quantum dots (CQDs) have held great promise in analytical and environmental fields thanks to their congenitally fascinating virtues. However, low quantum yield (QY) and modest fluorescent stability still restrict their practical applications. In this investigation, a green hydrothermal strategy has been devised to produce water-soluble nitrogen/phosphorus (N/P) co-doped CQDs from edible Eleocharis dulcis with multi-heteroatoms. Without any additives and further surface modifications, the resultant CQDs exhibited tunable photoluminescence just by changing hydrothermal temperatures. Appealingly, they showed remarkable excitation-dependent emission, high QY, superior fluorescence stability, and long lifetime. By extending the CQDs solutions as a “fluorescent ink”, we found their potential application in the anti-counterfeit field. When further evaluated as a fluorescence sensor, the N/P co-doped CQDs demonstrated a wide-range determination capability in inorganic cations, and especially the remarkable sensitivity and selectivity for elemental Fe³⁺. More significantly, the green methodology we developed here can be readily generalized for scalable production of high-quality CQDs with tunable emission for versatile applications.

Over past decades, the multicolor carbon dots (M-CDs) have attracted enormous attentions due to their tunable photoluminescence and versatile applications. Herein, the nitrogen-doped (N-doped) M-CDs including green, chartreuse, and pink emissive CDs are successfully synthesized by ultrasonic treatment of kiwifruit juice with different additive reagents such as ethanol, ethylenediamine, and acetone. Owing to their strong fluorescence upon irradiation with 365 nm UV light, the highly water-soluble M-CDs present great potential in the anticounterfeit field as fluorescent inks. Particularly, the resulting green emission CDs (G-CDs) with excellent fluorescence and stability are applied as a label-free probe model for “on–off” detection of Fe³⁺. The fluorescence of G-CDs is significantly quenched by Fe³⁺ through static quenching. The nanoprobe demonstrates good selectivity and sensitivity toward Fe³⁺ with a detection limit of ~0.11 μM. Besides, the quenched fluorescence of G-CDs by Fe³⁺ can be recovered by the addition of PO₄³⁻ or ascorbic acid (AA) into the CDs/Fe³⁺ system to realize the “off–on” fluorescent process. Furthermore, NOT and IMPLICATION logic gates are constructed based on the selection of Fe³⁺ and PO₄³⁻ or AA as the inputs, which makes the G-CD-based sensors utilized as various logic gates at molecular level. Therefore, the N-doped M-CDs hold promising prospects as competitive candidates in monitoring the trace species, applications in food chemistry, anticounterfeit uses, and beyond.