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Over the past two decades, fiber laser technologies have matured to such an extent that they have captured a large portion of the commercial laser marketplace. Yet, there still is a seemingly unquenchable thirst for ever greater optical power to levels where certain deleterious light-matter interactions that limit continued power scaling become significant. In the past decade or so, the industry has focused mainly on waveguide engineering to overcome many of these hurdles. However, there is an emerging body of work emphasizing the enabling role of the material. In an effort to underpin these developments, this paper reviews the relevance of the material in high power fiber laser technologies. As the durable material-of-choice for the application, the discussion will mainly be limited to silicate host glasses. The discussion presented herein follows an outward path, starting with the trivalent rare earth ions and their spectroscopic properties. The ion then is placed into a host, whose impact on the spectroscopy is reviewed. Finally, adverse interactions between the laser lightwave and the host are discussed, and novel composition glass fiber design and fabrication methodologies are presented. With deference to the symbiosis required between material and waveguide engineering in active fiber development, this review will emphasize the former. Specifically, where appropriate, materials-based paths to the enhancement of laser performance will be underscored.

Long lengths (250 meters) of a flexible 150 μm diameter glass-clad optical fiber containing a 15 μm diameter crystalline and phase-pure germanium core was fabricated using conventional optical fiber draw techniques. X-ray diffraction and spontaneous Raman scattering measurements showed the core to be very highly crystalline germanium with no observed secondary phases. Elemental analysis confirmed a very well-defined core-clad interface with a step-profile in composition and nominally 4 weight-percent oxygen having diffused into the germanium core from the glass cladding. For this proof-of-concept fiber, polycrystalline n-type germanium of unknown dopant concentration was used. The measured infrared transparency of the starting material was poor and, as a likely outcome, the attenuation of the resultant fiber was too high to be measured. However, the larger Raman cross-section, infrared and terahertz transparency of germanium over silicon should make these fibers of significant value for fiber-based mid- to long-wave infrared and terahertz waveguides and Raman-shifted infrared light sources once high-purity, high-resistivity germanium is employed.

The molten core method, whereby a precursor core phase melts at the draw temperature of the cladding glass that encapsulates it, has proven to be a remarkably versatile approach to realize novel optical fibers. Employed globally for both scientific inquiry and practical applications, it is arguably the only approach that leads to long lengths of novel material fiber with both crystalline and glassy cores. This article reviews the history of the process, the ever-broadening range of compositions, the unique applications that have been enabled, and provides a perspective on current challenges and future opportunities.