The presence of organic dyes from industrial wastewater can cause pollution and exacerbate environmental problems; therefore, in the present work, activated carbon was synthesized from locally available oil palm trunk (OPT) biomass as a low-cost adsorbent to remove synthetic dye from aqueous media. The physical properties of the synthesized oil palm trunk activated carbon (OPTAC) were analyzed by SEM, FTIR-ATR, and XRD. The concurrent effects of the process variables (adsorbent dosage (g), methylene blue (MB) concentration (mg/L), and contact time (h)) on the MB removal percentage from aqueous solution were studied using a three-factor three-level Box–Behnken design (BBD) of response surface methodology (RSM), followed by the optimization of MB adsorption using OPTAC as the adsorbent. Based on the results of the analysis of variance (ANOVA) for the three parameters considered, adsorbent dosage (X1) is the most crucial parameter, with an F-value of 1857.43, followed by MB concentration (X2) and contact time (X3) with the F-values of 95.60 and 29.48, respectively. Furthermore, the highest MB removal efficiency of 97.9% was achieved at the optimum X1, X2, and X3 of 1.5 g, 200 mg/L, and 2 h, respectively.
1 March 2019 in Journal of the Taiwan Institute of Chemical Engineers
Fish especially Indian Mackerel (R. kanagurta) provides protein, essential fatty acids and essential metals that are needed in the human diet, however high concentration of essential metals will cause adverse health effect towards human. Thus, the removal of heavy metals such as lead (Pb) and copper (Cu) from R. kanagurta (Indian mackerel) by using different types of natural waste adsorbents was implemented in this study. Initial concentration of heavy metals (Pb, Cu) in Indian mackerel (R. kanagurta) fish were above the permissible limit set by World Health Organization and Malaysia Food Regulation 1985. Thus, in this study, corncob and eggshell were applied as natural waste adsorbents to enhance the demetallisation process. The result showed only the corncob able to efficiently remove all the heavy metals in Indian Mackerel (R. kanagurta) up to 78.31% compared to the eggshell, which yielded about 71.34%. Besides, this study proved that using corncob; the Cd metal found to be wholly removed from (R. kanagurta) which met the permissible limit set by WHO and MFR.