The (H₂dabco)[Na(BF₄)₃] undergoes a static-to-dynamic phase transition at 403/386 K. Crystal structure analysis reveals that H₂dabco²⁺ and/or BF₄⁻ undergo disordering.

Reversible phase transitions in [C₃H₄NS]₂[KCo(CN)₆] exhibit switch-type dielectric transitions around 210 K and 237 K. The small displacements and/or thermal vibrations of the cations cause the phase transitions.

Voids that are formed by gas injection in a packed bed play an important role in metallurgical and chemical furnaces. Herein, two-phase gas–solid flow in a two-dimensional packed bed during blast injection was simulated numerically. The results indicate that the void stability was dynamic, and the void shape and size fluctuated within a certain range. To determine the void morphology quantitatively, a probabilistic method was proposed. By statistically analyzing the white probability of each pixel in binary images at multiple times, the void boundaries that correspond to different probability ranges were obtained. The boundary that was most appropriate with the simulation result was selected and defined as the well-matched void boundary. Based on this method, the morphologies of voids that formed at different gas velocities were simulated and compared. The method can help us to express the morphological characteristics of the dynamically stable voids in a numerical simulation.

Ionic rare earth ore is a type of featured rare earth ore in China. Its mining process suffers from a long leaching cycle and considerable consumption of leaching agents. Improving mining efficiency requires a sound physical understanding of the leaching process. In this study, the CFD‐based numerical model is used to analyze the physical process of leaching through porous media formed by particles. The simulation results indicate that a lower packing porosity and smaller particles packed granular porous medium result in much larger energy dissipation during seepage, and the energy dissipation increases with seepage velocity. It is found that when the seepage velocity increases to a certain high value, the energy dissipation exceeds the value predicted by Darcy’s law, which is mainly caused by liquid turbulence. Additionally, the effect of particle shape is examined. The results show that the granular medium composed of prolate particles causes larger energy dissipation than oblate particles, and spherical particles play the least role. This phenomenon may result from the particle shape affecting the area of the frontal contact surface between particles and liquid. The results provide new insights into the fundamental understanding of percolation and seepage behaviors in the ion‐adsorption‐type rare earth ore leaching process.