Cellulose paper, whose main component is cellulose polymer, has been widely used in oil-immersed power transformer that gradually deteriorates during transformer operation. Thermal aging is the main degradation form for cellulose paper immersed in insulation oil (oil–paper insulation) in a transformer. One of the most challenging issues in oil–paper insulation is inhibiting the aging of cellulose paper and extending its life. In this work, a comparative study was conducted on the thermal-aging characteristics of cellulose paper immersed in a novel three-element mixed insulation oil and mineral oil at 130 °C for 150 days. The key parameters of cellulose paper were analysed, including the degree of polymerization (DP), thermal-aging rate, surface colour, and AC breakdown voltage. The furfural content and acidity of the oil, as well as the AC breakdown voltage of the insulation oil were also analysed. The results show that the cellulose paper immersed in novel three-element mixed insulation oil had much higher DP values than that immersed in mineral oil after the same thermal-aging time. The mixed insulation oil could significantly inhibit the thermal aging of cellulose paper and prolong its life. The thermal-aging rate of the cellulose insulation polymer immersed in mixed insulation oil is significantly lower than that immersed in mineral oil, whether in the process of oil–paper insulation continuous aging or in the process of aging after oil replacement with unused insulation oil. The furfural generated by cellulose degradation in the novel three-element mixed insulation oil was also less than that in the mineral oil. The mixed insulation oil had a higher acidity value during the thermal-aging process, which was mainly due to the natural esters in the components of the mixed insulation oil. However, the AC breakdown voltage of the mixed insulation oil was always higher than that of the mineral oil. This study offers a new perspective in inhibiting the thermal aging of cellulose polymer in insulation oil.

The existing research on furfural analysis mainly focuses on the relationship between the furfural content in oil and the degree of polymerization (DP) of the paper, which are always obtained by accelerated thermal aging at high temperatures. However, the operating temperature of a winding is relatively low, approximately 60°C to 90°C. Thus, the relationship established at high temperature may be not suitable for the operating temperatures. In this research, aging tests of oil‐paper systems at different temperatures ( from 100°C to 130°C) were carried out, with the DP, furfural content in oil and furfural content in paper being measured regularly to analyze the effect of temperature variation on the production and diffusion behavior of furfural in oil–paper insulation. The results show that temperature influences the production of furfural, i.e., there is no obvious difference in the amount of furfural produced by paper in the initial aging periods; however, a higher temperature results in more furfural being produced when the DP decreases to values below 600. An obvious diffusion process occurs after furfural is produced in paper in accelerated aging experiments, resulting in most of the furfural content remaining in the cellulose paper in the initial aging period.