We report the coherent mid-infrared supercontinuum generation in an all-solid chalcogenide microstructured fiber with all-normal dispersion. The chalcogenide microstructured fiber is a four-hole structure with core material of ${\mathrm{AsSe}}_2$ and air holes that are replaced by ${\mathrm{As}}_2{\mathrm{S}}_5$ glass rods. Coherent mid-infrared supercontinuum light extended to 3.3 μm is generated in a 2 cm long chalcogenide microstructured fiber pumped by a 2.7 μm laser.

Titanium trisulphide (TiS₃) has been widely used in the field of optoelectronics owing to its superb optical and electronic characteristics. In this work, a self-powered photodetector using bulk PbS/TiS₃ p-n heterojunction is numerically investigated and analyzed by a Solar Cell Capacitance Simulator in one-Dimension (SCAPS-1D) software. The energy bands, electron-holes generation or recombination rate, current density-voltage (J-V), and spectral response properties have been investigated by SCAPS-1D. To improve the performance of photodetectors, the influence of thickness, shallow acceptor or donor density, and defect density are investigated. By optimization, the optimal thickness of the TiS₃ layer and PbS layer are determined to be 2.5 μm and 700 nm, respectively. The density of the superior shallow acceptor (donor) is 10¹⁵ (10²²) cm⁻³. High quality TiS₃ film is required with the defect density of about 10¹⁴ cm⁻³. For the PbS layer, the maximum defect density is 10¹⁷ cm⁻³. As a result, the photodetector based on the heterojunction with optimal parameters exhibits a good photoresponse from 300 nm to 1300 nm. Under the air mass 1.5 global tilt (AM 1.5G) illuminations, the optimal short-circuit current reaches 35.57 mA/cm² and the open circuit voltage is about 870 mV. The responsivity (R) and a detectivity (D*) of the simulated photodetector are 0.36 A W⁻¹ and 3.9 × 10¹³ Jones, respectively. The simulation result provides a promising research direction to further broaden the TiS₃-based optoelectronic device.

Tungsten disulfide monolayers have attracted extensive attention in nanoelectronics and optoelectronics applications due to their remarkable electronic and optical properties. High-quality WS₂ monolayers with a scalable size and uniform thickness can be synthesized by a chemical vapor deposition method (CVD). However, they commonly contain intrinsic structural defects and different populations of charge carriers, which are responsible for different contributions of excitons, trions, and biexcitons to their photoluminescence (PL) emission. Here, we adopt sodium sulphide (Na₂S) solution to chemically treat CVD-grown WS₂ monolayers by a simple immersing method. The results show that WS₂ monolayers have a significantly enhanced PL emission by a factor of 25-fold and an obvious red-shift of the PL wavelength, resulting from the different excitonic states induced by effective n-type doping after Na₂S treatment. This work provides a simple but promising chemical doping route to significantly improve the optical properties of WS₂ monolayers and paves the way for the realization of practical WS₂ monolayer based optoelectronic applications.

We numerically investigate mid-infrared supercontinuum generation in single mode fluoride fiber pumped by 1.56 μm picosecond fiber lasers. To get high energy conversion efficiency in mid-infrared region, the ratio of power generated in 2.5 ~5 μm range to the total input power for supercontinuum generation is optimized by varying the pulse width, peak power and fiber length. The long wavelength edge of the supercontinuum spectrum can be extended to 4.8 μm in a 100 cm long fluoride fiber pumped by a 1.56 μm fiber laser with a pulse width of 4 ps and a peak power of 100 kW, and the corresponding ratio of power generated in 2.5 ~5 μm range to the total input power is about 44.6%. The spectral broadening is mainly caused by self-phase modulation, stimulated Raman scattering and four-wave mixing. The simulated results show that high average power supercontinuum light source in 2.5 ~5 μm range could be obtained in fluoride fibers pumped by 1.56 μm picosecond fiber lasers.

We have numerically investigated the coherence property of mid-infrared supercontinuum generation in tapered step-index chalcogenide fibers with different structures. The pump source is a 4 μm laser with pulse width of 500 fs and peak power of 1 kW. The length ratio is the ratio of transition region length near the laser input to the other transition region length near the output. We calculate the bandwidth and the spectrally averaged coherence of the supercontinuum spectra generated in fibers with different length ratios under the same pumping condition. Numerical results show that as the length ratio increases, the bandwidth decreases from 4.84 μm to 4.11 μm while the spectrally averaged coherence increases from 0.53 to 0.9 and then jitters near the maximum. The length ratio within 1–1.5 is preferable to keep a balance between bandwidth and coherence.

We demonstrate all-optical control of group velocity dispersion (GVD) via optical Kerr effect in highly nonlinear tellurite photonic crystal fibers. The redshift of the zero-dispersion wavelength is over 307 nm, measured by soliton self-frequency shift cancellation, when the pump peak power of a 1.56 μm femtosecond fiber laser is increased to 11.6 kW. The all-optical control of GVD not only offers a new platform for constructing all-optical-control photonic devices but also promises a new class of experiments in nonlinear fiber optics and light–matter interactions.