This paper presents innovative packaging materials made of environmentally friendly biodegradable polymers (polylactide and polyhydroxybutyrate) with the addition of natural colorants commonly used in the food industry. Colorants fulfilled the role of indicator, changing colour under the influence of external factors, and gave the materials the characteristics of intelligent packaging, where colour changes indicated the life time of the materials. The paper gives the mechanical and thermal properties of the materials obtained, and describes changes in the colour of the samples under the influence of thermooxidation, UV and weathering, as well as the biodegradability of the materials. The packaging materials presented are in line with current trends in the packaging market and legal requirements. The samples, in addition to the basic functions of packaging materials, are pro-ecological and fully biodegradable new generation materials.
1 December 2016 in International Journal of Electrochemical Science
An infusion of green coffee is a commonly consumed beverage, famous for its health-promoting properties. Green coffee owes its properties to the richness of active phytochemicals. The aim of this study was to determine the components of green coffee bean extracts and their properties. The scope of research included gas chromatography-mass spectrometry (GC-MS), Fourier transform infrared spectroscopy (FTIR) and Ultraviolet-Visible spectroscopy (UV-Vis) spectroscopy; the electrochemical determination of the behavior of green coffee extract; and the determination of antioxidant properties by colorimetric spectroscopic methods (ABTS, DPPH, FRAP and CUPRAC). Water and ethanol extracts from green coffee were characterized by significant antioxidant properties and a high capacity to reduce transition metal ions. Voltammetric tests showed that the solution has good antioxidant properties in view of it contains many polyphenolic compounds that oxidize in the potential range tested.
The stabilization efficiency of flavonoids (rutin and hesperidin) in polyester (polylactide (PLA) and polyhydroxyalkaonate (PHA)) composites under oxygen at high temperature was investigated. The polymer was homogenized with three antioxidants then processed by extrusion. The effects of stabilizers on the following physicochemical properties were investigated: melt flow, Vicat softening temperature, surface energy, and color change (Cie-Lab space). The aim of this study was to improve the stability of aliphatic polyesters by extending and controlling their lifetime. Differential Scanning Calorimetry DSC and Thermogravimetric analysis DTG methods were used to confirm the stabilizing effects (the inhibition of oxidation) of flavonoids (rutin and hesperidin) on the ageing process of biodegradable polymers. The levels of migration of plant antioxidants from PLA and PHA were determined and compared to the industrial stabilizer (Chimassorb 944 UV absorber). Based on this study, a comparable-to-higher efficiency of the proposed flavonoids for the stabilization of polyesters was found when compared to the commercial stabilizers. Thus, in the future, natural plant-derived substances may replace toxic hindered amines, which are commonly used as light stabilizers (HALS—Hindered Amine Light Stabilizers) in the polymer industry.