This study presents a semi-empirical modeling approach based on an extensive parametric study using a spark-ignition port-injection engine. The experimental results are used to derive engine-out emission models for each regulated pollutant (CO, HC, NO_x) as a function of engine operating parameters. Such parameters include engine speed, intake manifold pressure, equivalence ratio, and spark advance. The proposed models provide accurate predictions over a large range of engine operating conditions. The adequate accuracy and low computational burden of the models are promising in the context of optimal control theory. Dynamic programming is applied in order to find the best operating parameters that define trade-off between fuel consumption and emissions over driving cycles.