Transport and magnetic properties are reported for ternary skutterudites and Physical properties of are dominated by crystal electric field effects, yielding in the magnetic triplet as ground state. As a result, long-range magnetic order appears below 4.6 K. exhibits an unusually high electronic contribution to the specific heat of several hundred and a significant value of a nuclear Schottky contribution is derived below about 1 K, primarily related to with a nuclear spin The figure of merit at room temperature, expressing the thermoelectric performance of is about 0.075.
We report on measurements of the magnetic penetration depth of polycrystalline samples of nonmagnetic MoAlC ( K) without inversion symmetry. Two previous specific-heat measurements in this compound found different anomalous peaks in the low-temperature limit. One of these peaks was attributed to the superconducting transition at 3 K of the impurity phase MoC. We argue here that the second anomalous peak may be caused by the superconducting transition of SiC:Al at 1.45 K, another impurity phase possibly present in MoAlC samples. The temperature-independent behavior of the penetration depth observed below 0.5 K is taken as firm evidence for the presence of a nodeless superconducting gap in MoAlC. Numerical calculations using the BCS expression for the penetration depth give qualitative support for an isotropic energy gap in MoAlC. The present results suggest that MoAlC is a conventional -wave superconductor, although two-gap or anisotropic-gap superconductivity cannot be ruled out.
1 February 2017 in Journal of Alloys and Compounds