Double-shelled CeO ₂ @C hollow nanospheres exhibit high reversible capability, a stable cycling life, and good rate capacity as anodes for lithium-ion batteries.

Exploiting excellent photocatalytic activity and stable heterostructure composites are of critical importance for environmental sustainability. The spherical Bi₂WO₆/Bi₂S₃/MoS₂ n-p heterojunction is first prepared via an in situ hydrothermal method using Bi₂WO₆, Na₂MoO₄·2H₂O, and CH₄N₂S, in which the intermediate phase Bi₂S₃ is formed due to chemical coupling interaction of Bi₂WO₆ and CH₄N₂S. Scanning electron microscopy indicates that the compactness of the sample can be easily adjusted by changing the contents of S and Mo sources in the solution. The results of ultraviolet–visible (UV–vis) diffuse reflectance spectra, photoluminescence, transient photocurrent response, and electrochemical impedance spectra indicate that the formation of heterojunctions contributes to enhancing visible-light utilization and promoting photogenerated carrier separation and transfer. The composite material is used as a catalyst for the visible light photocatalytic reduction of Cr(VI). Remarkably, the optimal Bi₂WO₆/Bi₂S₃/MoS₂ n-p heterojunction achieves the greatest Cr(VI) reduction rate of 100% within 75 min (λ > 420 nm, pH = 2); this rate is considerably better than the Cr(VI) reduction rate of pure Bi₂WO₆. The recycling experiment also reveals that the photocatalytic performance of the n-p heterojunction toward Cr(VI) is still maintained at 80% after three cycles, indicating that the n-p heterojunction has excellent structural stability. The capture experiment proves that the main active species in the system are electrons. The reasonable mechanism of Bi₂WO₆/Bi₂S₃/MoS₂ photocatalytic reduction Cr(VI) is proposed. Our work provides new research ideas for the design of ternary heterojunction composites and new strategies for the development of photocatalysts for wastewater treatment.

Micro/nanostructured spherical materials have been widely explored for electrochemical energy storage due to their exceptional properties, which have also been summarized based on electrode type and material composition. The increased complexity of spherical structures has increased the feasibility of modulating their properties, thereby improving their performance compared with simple spherical structures. This paper comprehensively reviews the synthesis and electrochemical energy storage applications of micro/nanostructured spherical materials. After a brief classification, the concepts and syntheses of micro/nanostructured spherical materials are described in detail, which include hollow, core-shelled, yolk-shelled, double-shelled, and multi-shelled spheres. We then introduce strategies classified into hard-, soft-, and self-templating methods for synthesis of these spherical structures, and also include the concepts of synthetic methodologies. Thereafter, we discuss their applications as electrode materials for lithium-ion batteries and supercapacitors, and sulfur hosts for lithium–sulfur batteries. The superiority of multi-shelled hollow micro/nanospheres for electrochemical energy storage applications is particularly summarized. Subsequently, we conclude this review by presenting the challenges, development, highlights, and future directions of the micro/nanostructured spherical materials for electrochemical energy storage.

At present, lithium-ion batteries (LIBs) have received widespread attention as substantial energy storage devices; thus, their electrochemical performances must be continuously researched and improved. In this paper, we demonstrate a simple self-template solvothermal method combined with annealing for the synthesis of NiFe₂O₄ yolk-shell (NFO-YS) and NiFe₂O₄ solid (NFO-S) nanospheres by controlling the heating rate and coating them with a carbon layer on the surface via high-temperature carbonization of resorcinol and formaldehyde resin. Among them, NFO-YS@C has an obvious yolk-shell structure, with a core-shell spacing of about 60 nm, and the thicknesses of the NiFe₂O₄ shell and carbon shell are approximately 15 and 30 nm, respectively. The yolk-shell structure can alleviate volume changes and shorten the ion/electron diffusion path, while the carbon shell can improve conductivity. Therefore, NFO-YS@C nanospheres as the anode materials of LIBs show a high initial capacity of 1087.1 mA h g⁻¹ at 100 mA g⁻¹, and the capacity of NFO-YS@C nanospheres impressively remains at 1023.5 mA h g⁻¹ after 200 cycles at 200 mA g⁻¹. The electrochemical performance of NFO-YS@C is significantly beyond NFO-S@C, which proves that the carbon coating and yolk-shell structure have good stability and excellent electron transport ability.