Probing the dark state: Excitons, electron-hole pairs held together by Coulomb attraction, can be generated in semiconductors under excitation and greatly influence the material's optoelectronic properties. Although bright excitons are optically active, their dark-state cousins have been more difficult to detect. They do, however, affect the optoelectronic properties through their interaction with light and bright excitons. Madéo et al. developed a pump-probe photoemission technique that is used reveal the spatial, temporal, and spectral dynamics of excitons (see the Perspective by Na and Ye). Demonstrated in two-dimensional monolayer films of tungsten diselenide, the technique could also be applicable to other semiconductor systems hosting excitonic excitations. Science , this issue p. 1199 ; see also p. 1166
The amplification of spontaneous emission is used to initiate laser action. As the phase of spontaneous emission is random, the phase of the coherent laser emission (the carrier phase) will also be random each time laser action begins. This prevents phase-resolved detection of the laser field. Here, we demonstrate how the carrier phase can be fixed in a semiconductor laser: a quantum cascade laser (QCL). This is performed by injection seeding a QCL with coherent terahertz pulses, which forces laser action to start on a fixed phase. This permits the emitted laser field to be synchronously sampled with a femtosecond laser beam, and measured in the time domain. We observe the phase-resolved buildup of the laser field, which can give insights into the laser dynamics. In addition, as the electric field oscillations are directly measured in the time domain, QCLs can now be used as sources for time-domain spectroscopy.