By way of the sol–gel chemical synthesis method, it is possible to synthesize SiO₂ nanoparticles with a defined specific particle size, a surface area, and a defined crystal structure that can be effectively used as a nanoadsorbent to remove various organic dyes. SiO₂ nanoparticles were synthesized by the sol–gel method using sodium silicate (Na₂SiO₃) by a green method without using a tetraethyl orthosilicate (TEOS) precursor, which is very expensive and highly toxic. This sol–gel process involves the formation of a colloidal suspension (sol) and solid gelation to form a network in a continuous liquid phase (gel). In addition, it requires controlled atmospheres. XRD indicates the presence of an amorphous phase with a diffraction angle of 2θ = 23°, associated with SiO₂. UV-Vis spectroscopy reveals an absorbance value in the region of 200 nm to 300 nm, associated with SiO₂ nanoparticles. The application as a nanoadsorbent to remove dyes was measured, and it was found that the nanoparticles with the best performance were those that were synthesized with pH 7, showing a 97% removal with 20 mg of SiO₂ nanoparticles in 60 min. Therefore, SiO₂ nanoparticles can be used as a nanoadsorbent, using a low-cost and scalable method for application to remove methylene blue in an aqueous medium.

The passive Q-switched operation of a ring cavity Er/Yb-doped double clad fiber laser by using an Al-doped ZnO (AZO) thin film as saturable absorber is experimentally demonstrated. In order to improve the absorbance in the C-band wavelength region, a thin film of AZO containing Zn and Al metal precursors in a proportion of 98:2 wt% was developed by an radio-frequency (RF) magnetron sputtering process. Then the AZO film was used as a saturable absorber (SA) in a ring cavity Er/Yb double clad fiber laser. The AZO-SA exhibits a modulation depth of 11.3% and a saturation intensity of 0.057 MW cm ⁻² in the 1.55 µ m waveband. In a pump power range from 0.475 to 1.356 W, stable Q-switched pulse trains with repetition rates of 70.1–161.3 kHz were observed. With a maximum pump power of 1.356 W, a minimum pulse width of 1.12 µ s and a maximum pulse energy of 1.32 µ J are obtained. To the best of our knowledge, we present the first demonstration of a passive Q-switching laser operation using an RF sputtered AZO thin film as a saturable absorber. The reliability of the RF magnetron sputtered AZO thin films used as an SA for 1.55 µ m Q-switched laser applications is experimentally demonstrated.