This study reports a polymer electrolyte fuel cell based on polydimethylsiloxane coated with a flexible current-collecting layer of Ag nanowire percolation networks. The reactive area of the bendable fuel cell was 9 cm2 and showed the maximum absolute power of 639 mW (the power density was 71 mW cm−2) under various bending conditions. Impedance spectra of the operating cell revealed that ohmic and Faradaic resistances decreased under the bent condition. Overall, the degree of bending improves the cell performances. The structural modeling result showed that decrease of the resistance and corresponding performance enhancement were due to the increased compressive force normal to the membrane electrode assembly, which was investigated through finite element simulation of the stress within the bendable fuel cell.
Anode aluminum oxide-supported thin-film fuel cells having a sub-500-nm-thick bilayered electrolyte comprising a gadolinium-doped ceria (GDC) layer and an yttria-stabilized zirconia (YSZ) layer were fabricated and electrochemically characterized in order to investigate the effect of the YSZ protective layer. The highly dense and thin YSZ layer acted as a blockage against electron and oxygen permeation between the anode and GDC electrolyte. Dense GDC and YSZ thin films were fabricated using radio frequency sputtering and atomic layer deposition techniques, respectively. The resulting bilayered thin-film fuel cell generated a significantly higher open circuit voltage of approximately 1.07 V compared with a thin-film fuel cell with a single-layered GDC electrolyte (approximately 0.3 V).