Polyimide/Epoxy resin–molybdenum disulfide bonded solid lubricant coatings (denoted as PI/EP-MoS₂) were prepared. The influence of polyfluo-wax (denoted as PFW) on the microhardness and friction and wear behavior of as-prepared PI/EP-MoS₂ lubricant coating was measured using a microhardness tester and a reciprocating ball-on-disc tribometer, respectively. The worn surfaces of the lubricant coatings were observed with a scanning electron microscope, and their wear rate was determined with a Micro XAM surface mapping microscope. Moreover, the transfer films formed on the counterpart steel ball surfaces were analyzed by X-ray photoelectron spectroscopy. Results indicate that the incorporation of a proper content of PFW filler is effective at improving the antifriction performance of the PI/EP-MoS₂ lubricant coating while maintaining better wear resistance. Moreover, the friction coefficient of the lubricant coating decreases with increasing content of PFW from 2 to 10%, and the one with a filler content over 6% PFW has a steady friction coefficient of 0.07. The improvement in the antifriction performance of the lubricant coating with the incorporation of the PFW filler is attributed to the excellent lubricity of homogeneously distributed PFW.

A facile in situ synthesis approach and a size control strategy were established to obtain Ag₂S nanoparticles in polyimide (PI) composite coatings. Such Ag₂S nanoparticles in the composite coatings were characterized, and the effects of the as-obtained Ag₂S nanoparticles of different sizes on the mechanical and tribological properties of the nanocomposite coatings were investigated. Results indicate that the in situ synthesized Ag₂S nanoparticles exhibited good dispersibility and bimodal and multimodal size distribution in the nanocomposite coatings. The size of the Ag₂S nanoparticles can be effectively controlled by adjusting the substituent alkyl chain length of single-source precursor, and these Ag₂S nanoparticles exhibited superior improvement to mechanical and tribological properties of the nanocomposite coatings. More importantly, the Ag₂S nanoparticles with the proper grain size and bimodal size distribution provided the optimal mechanical and tribological properties for the nanocomposite coatings, and the excellent tribological properties were attributed to their outstanding mechanical properties and strong ability to form a homogenous and stable protective tribofilm.