In this work, we have fabricated a series of perovskite-type oxide LaFeO₃ samples using a simple sol–gel method and further calcination treatment.

Perovskite oxides, as a kind of functional materials, have been widely studied in recent years due to its unique physical, chemical, and electrical properties. Here, we successfully prepared perovskite-type LaCoO₃ (LCOs) nanomaterials via an improved sol-gel method followed by calcination, and investigated the influence of calcination temperature and time on the morphology, structure, and electrochemical properties of LaCoO₃ nanomaterials. Then, based on the optimal electrochemical performance of LCO-700-4 electrode sample, the newly synthesized nanocomposites of Sr-doping (LSCO-0.2) and rGO-compounding (rGO@LCO) through rational design exhibited a 1.45-fold and 2.03-fold enhancement in its specific capacitance (specific capacity). The rGO@LCO electrode with better electrochemical performances was further explored by assembling rGO@LCO//rGO asymmetric supercapacitor system (ASS) with aqueous electrolyte. The result showed that the ASS delivers a high energy density of 17.62 W h kg⁻¹ and an excellent cyclic stability with 94.48% of initial capacitance after 10,000 cycles, which are good electrochemical performances among aqueous electrolytes for green and new efficient energy storage devices.

Facing the increasing demand for various renewable energy storage devices and wearable and portable energy storage systems, the research on electrode materials with low costs and high energy densities has attracted great attention. Herein, free-standing rGO-CNT nanocomposites have been successfully synthesized by a facile hydrothermal method, in which the hierarchical porous network nanostructure is synergistically assembled by rGO nanosheets and CNT with interlaced network distribution. The rGO-CNT composite electrodes with synergistic enhancement of rGO and CNT exhibit high specific capacitance, excellent rate capability, exceptional conductivity and outstanding long-term cycling stability, especially for the optimal rGO-CNT₃₀ electrode. Applied to a symmetric supercapacitor systems (SSS) assembled with an rGO-CNT₃₀ electrode and with 1 M Na₂SO₄ aqueous solution as the electrolyte, the SSS possesses a high energy density of 12.29 W h kg⁻¹ and an outstanding cycling stability, with 91.42% of initial specific capacitance after 18,000 cycles. Results from these electrochemical properties suggest that the rGO-CNT₃₀ nanocomposite electrode is a promising candidate for the development of flexible and lightweight high-performance supercapacitors.