ceramics were prepared by a traditional solid-state reaction method. Two relaxation processes (marked as A and B) of the ceramics were investigated by analyzing the values obtained from the Arrhenius law. Colossal dielectric constant (CDC) was first obtained in ceramics, whose permittivity was up to 3000 (1 kHz, room temperature), greater than that of pure ceramics and samples with more Pr addition ( and 0.03). This CDC behavior was related to the internal barrier layer capacitance mechanism.