In order to achieve process intensification for adsorption chillers and heat pumps, a new composite material was developed based on sintered aluminum fibers from a melt-extraction process and a dense layer of silico-aluminophosphate (SAPO-34) on the fiber surfaces. The SAPO-34 layer was obtained through a partial support transformation (PST) process. Preparation of a composite sample is described and its characteristic pore size distribution and heat conductivity are presented. Water adsorption data obtained under conditions of a large pressure jump are given. In the next step, preparation of the composite was scaled up to larger samples which were fixed on a small adsorption heat exchanger. Adsorption measurements on this heat exchanger element that confirm the achieved process intensification are presented. The specific cooling power for the adsorption step per volume of composite is found to exceed 500 kW/m³ under specified conditions.

A novel thermodynamic cycle for adsorption heat pumps and chillers is presented. It shows a significant improvement of the internal heat recovery between the adsorption and the desorption half cycle. A stratified thermal storage, which allows for a temperature-based extraction and insertion of storage fluid, is hydraulically coupled with a single adsorber. The benefit is an increased efficiency by reusing the released heat of adsorption for regeneration of the adsorber and by rendering possible low driving temperature differences. For investigating the second law of this cycle, a dynamic model is employed. The transient behavior of the system and the respective losses because of driving temperature differences at the heat exchangers and losses due to mixing within the storage and to the surroundings are depicted in this one-dimensional model. The model is suitable both for analyzing this advanced cycle as well as for comparisons with other cycles.