Wood is an indispensable renewable material for national economic development. As a bio-organic material, wood is subject to deterioration due to climatic, biological, and chemical factors, which greatly limit the advantages of wood products and increase the difficulty of conserving historical wood. To preserve the historical and cultural heritage, extend the historical life of ancient wooden structures, and promote the efficient and sustainable utilization of wood resources, this paper provides an overview of the main degradation and destruction forms and biochemical changes of wood in ancient architecture, unearthed relics, and antique ship wood from the perspective of wooden structure, historical applications, and their forms of destruction. The conservation strategies and consolidation methods of ancient wood are reviewed, with emphasis on the summary and analysis of the properties and uses of different consolidation materials and their methodological characteristics for the conservation of historical wood. In the context of the development of biomaterials, polymer chemistry and nanotechnology, biomass nanocomposites are applied gradually in the field of consolidation. To provide a strong basis for the effective use of reinforced wood, this paper presents the theoretical foundation for the research and development of green, efficient, and environmentally friendly wood consolidation and protection technologies.
The ageing of materials is an irreversible, in-time occurring complex phenomenon, which affects both wood surfaces and the coating materials. This paper focuses on the light-induced natural ageing of wood-coated surfaces in indoor conditions. Two wood species: European maple (Acer pseudoplatanus) and European walnut (Juglans regia) and two types of waxes: bees wax and Chinese wax were employed in the experiments presented in this paper. Uncoated and coated wood samples were exposed to the natural sunlight filtered by window glass in a simulated indoors natural ageing test for a total period of 7 years. Colour measurements in the CIE-Lab system and FTIR-ATR investigation were employed to evaluate the ageing phenomena. The uncoated wooden samples underwent progressive colour changes perceived as darkening for European maple and lightening for European walnut, corresponding to total colour differences values (ΔE) after 7 years of exposure of 12.54 and 11.66, respectively. Coating of wood samples with the two types of waxes differently influenced the total colour changes for the two wood species: reduced colour changes corresponding to ΔE values of 4.79–6.44 were determined for European maple, whilst increased colour changes corresponding to ΔE values of 13.80–20.83 were determined for European walnut. FTIR analysis highlighted different surface chemistry changes for the uncoated and wax-coated wood samples.
The Huaguangjiao I is an ancient Chinese wooden shipwreck from the South Song Dynasty (AD 1127–1279) discovered in the South China Sea in 1996. The first phase of its conservation, desalination and desulfurization, was completed in 2016. In this paper, three archaeological wood samples exhibiting different degrees of deterioration from Huaguangjiao No. 1 were consolidated with PEG-4000 and dehydrated via freeze drying and supercritical CO2 drying methods. The dimensional stability, hygroscopicity, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) were used to evaluate the effects of consolidation and dehydration. The results showed that PEG4000 was an efficient consolidation material that also effectively decreased shrinkage during dehydration. Furthermore, both vacuum-freeze and supercritical CO2 drying were efficient methods for treating waterlogged archaeological wood. After PEG4000 impregnation, the shrinkage percentage of the waterlogged archaeological wood became slightly lower than sound wood. The moisture absorption of the experimental specimens ranged within 3.35%–4.53%, and they comprised 50% sound wood, resulting in a marked improvement in dimensional stability. FTIR spectra indicated that impregnation improved wood dimensional stability by reducing hydrophilic groups. These results show that this method can effectively treat waterlogged wood for preservation purposes.
Dimensional stability proves to be an important factor affecting the quality of wooden products. As a sort of crude and thermoplastic resin, shellac excreted by lac insects demonstrates water-repellent and environmental-friendly features. The research impregnated shellac with wood at room temperature and with a vacuum-pressure procedure. Efforts were made to examine how shellac treatment affected the dimensional stability, moisture absorption, chemical structure, thermostability, as well as morphological characteristics of wood. Results indicated that shellac treatment was a type of efficient solution useful in the enhancement of the dimensional stability of wood. Shellac solution had good permeability in the wood, and the weight percentage gain reached 13.01% after impregnation. The swelling coefficients of treated wood in the tangential and radial directions decreased by 20.13% and 24.12%, respectively, indicating that impregnation could improve wood dimensional stability. The moisture absorption of shellac-treated wood was reduced by 38.15% under 20 °C and 65% relative humidity. Moreover, shellac treatment significantly modified wood structure, although there were no drastic changes in the spectra. Specimens for shellac treatment ran across two decomposition peaks at 350 and 390 °C, and specimens in the control group saw one more common derivative thermogravimetric curve when the sharp peak approached 355 °C. After impregnation of shellac into wood, the shellac blocked pits and hardened on the intrinsic layer of the wood for fear of hygroscopicity. The practice was applicable to a variety of wood products, such as buildings, furniture, and landscape architecture.
In this study, wood samples extracted from the Taicang ancient ship, dating back to the Yuan Dynasty, were investigated to study the characteristics of waterlogged archaeological wood. The macroscopic characteristics and microscopic structures were used to identify the wood species. To assess the degree of degradation of the waterlogged archaeological wood, X-ray diffraction (XRD), nanoindentation (NI), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM) were used to compare the new and ancient wood samples from the same species. The microscopic structures of the samples were identified as Pinus massoniana. The XRD and nanoindentation results revealed that the crystallinity index of the cellulose decreased from 41.07% to 33.85%, the elastic modulus was reduced by 20.90%, and hardness was reduced by 55.6% compared with the new wood. The FTIR spectra revealed that biological deterioration occurred in the cellulose and hemicellulose, but there was no noticeable change in the lignin content. These results provide helpful information for the conservation and restoration of ancient ships.