Crack healing phenomena were observed in mullite and mullite + Yb₂SiO₅ environmental barrier coating (EBC) materials during thermal shock cycles. Air plasma spray coating was used to deposit the EBC materials onto a Si bondcoat on a SiC_f/SiC composite substrate. This study reveals that unidirectional vertical cracks (mud cracks) formed after several thermal shock cycles; however, the cracks were stable for 5000 thermal shock cycles at a maximum temperature of 1350 °C. Moreover, the crack densities decreased with an increasing number of thermal shock cycles. After 3000 thermal shock cycles, cracks were healed via melting of a phase containing SiO₂ phase, which partially filled the gaps of the cracks and resulted in the precipitation of crystalline Al₂O₃ in the mullite. Post-indentation tests after thermal shock cycling indicated that the mullite-based EBC maintained its initial mechanical behavior compared to Y₂SiO₅. The indentation load–displacement tests revealed that, among the materials investigated in the present study, the mullite + Yb₂SiO₅ EBC demonstrated the best durability during repetitive thermal shocks.