Previous research has shown that composite shape-stabilized phase change material (CPCM) has a remarkable capacity for thermal storage and stabilization, and it can be directly applied to highway construction without leakage. However, recent studies on temperature changing behaviors of CPCM and asphalt mixture cannot intuitively reflect the thermoregulation mechanism and efficiency of CPCM on asphalt mixture. The objective of this paper is to determine the specific heat capacity of CPCM and asphalt mixtures mixed with CPCM using the heat exchange system and the data acquisition system. Studies have shown that the temperature-rise curve of 5 °C CPCM has an obvious temperature plateau, while an asphalt mixture mixed with 5 °C CPCM does not; with increasing temperature, the specific heat capacities of both 5 °C CPCM and asphalt mixture first increase and then decrease, while the variation rate of 5 °C CPCM is larger than that of the asphalt mixture, and the maximum specific heat capacity of 5 °C CPCM appears around the initial phase change temperature. It is concluded that the temperature intervals of 5 °C CPCM are −18 °C–7 °C, 7 °C–25 °C and 25 °C–44 °C, respectively, and that of the asphalt mixture are −18 °C~10 °C, −10 °C~5 °C and 5 °C~28 °C. A low dosage of 5 °C CPCM has little influence on the specific heat capacity of asphalt mixture. Finally, the functions of specific heat capacities and temperature for CPCM and asphalt mixture mixed with CPCM were recommended by the sectional regression method.
30 July 2015 in Journal of Wuhan University of Technology-Mater. Sci. Ed.
The objective of this investigation is to prepare the shape memory hydrogenated epoxy resin used for asphalt mixtures (SM-HEP-AM) and study its properties. The shape memory hydrogenated epoxy resin (SM-HEP) is prepared using hydrogenated bisphenol A epoxy resin (AL-3040), polypropylene glycol diglycidylether diacrylate (JH-230), and isophorone diamine (IPDA). The formulations of the SM-HEP-AM are obtained by the linearly fitted method. The thermo-mechanical property, molecular structure, and shape-memory performance of the SM-HEP-AM are studied. The glass-transition temperature (Tg) is determined using the differential scanning calorimeter (DSC). The results proved that the Tg level increased when the JH-230 content decreased. The thermo-mechanical property of the SM-HEP-AM is measured by dynamical mechanical analysis (DMA). The storage modulus of the SM-HEP-AM decreased with the increase in the JH-230 content. The above phenomena are attributed to the change in the JH-230 content. The shape memory performance results of the SM-HEP-AM indicate that specimen deformation can completely recover after only several minutes at Tg + 10 °C and Tg + 20 °C. The shape recovery time of the SM-HEP-AM increases with increased JH-230 content, and the change between the shape recovery time and JH-230 content gradually decreased as the temperature increased. The deformation recovery performance of asphalt mixture with and without the SM-HEP-AM (Tg = 40 °C) was tested by the deformation recovery test. This was used to prove that the SM-HEP-AM helps to improve the deformation recovery performance of the asphalt mixture.
Asphalt concrete is one type of the temperature sensitive mixtures, which is the most and broadest used pavement material in the world. Asphalt pavement suffers from the impact of temperature due to the temperature variation in different districts and environments. Facing temperature sensitivity, this paper uses Indirect Tensile Test (IDT) to analyze the tensile characters of asphalt mixture under different temperatures (−20°C, −10°C, 0°C, 15°C, 20°C, 45°C, and 60°C). The influence factors of temperature, loading rate, asphalt content, asphalt types, and mixtures gradation are evaluated. Piecewise linear model, logarithm linear model and S-logistic nonlinear model are applied to simulate the variation of flexural tensile characters with temperature change. Results show that temperature has significant influence on flexural tensile properties. Loading rates also has obvious influence on flexural tensile characteristics. With temperature changes, asphalt types have evident influence on mixture’s tensile characteristics, SBR modified asphalt has better performance at the lower temperature environment. Mixtures’ gradation has important effect on tensile strength and tensile strain as well, while due the similarity between two gradations, it is hard to precisely recommend which one is better. Asphalt content has evident influence on mixtures properties at the same temperature condition. Research results provide suggestions and applications for construction and performance of asphalt pavement. The results also indicate that IDT would be a practical option to evaluate the properties of asphalt mixture in all temperature ranges.
Granular materials are used directly or as the primary ingredients of the mixtures in industrial manufacturing, agricultural production and civil engineering. It has been a challenging task to compute the porosity of a granular material which contains a wide range of particle sizes or shapes. Against this background, this paper presents a newly developed method for the porosity prediction of granular materials through Discrete Element Modeling (DEM) and the Back Propagation Neural Network algorithm (BPNN). In DEM, ball elements were used to simulate particles in granular materials. According to the Chinese specifications, a total of 400 specimens in different gradations were built and compacted under the static pressure of 600 kPa. The porosity values of those specimens were recorded and applied to train the BPNN model. The primary parameters of the BPNN model were recommended for predicting the porosity of a granular material. Verification was performed by a self-designed experimental test and it was found that the prediction accuracy could reach 98%. Meanwhile, considering the influence of particle shape, a shape reduction factor was proposed to achieve the porosity reduction from sphere to real particle shape.