We investigate experimentally and theoretically the origin of magnetism in nanocrystalline-undoped ceria films. Our results are consistent with density-functional calculations showing that both oxygen and cerium vacancies lead to ferromagnetism. Although the number of cerium vacancies is smaller than that of oxygen vacancies, the relatively high magnetic moment of the former might result in a substantial contribution to the magnetic properties. Diluted defect magnetism is suggested as a universal feature of ferromagnetism in nonmagnetic oxides without magnetic impurities.
A graded distribution of antidots in superconducting a-Mo79Ge21 thin films has been investigated by magnetization and magneto-optical imaging measurements. The pinning landscape has maximum density at the sample border, decreasing linearly towards the center. Its overall performance is noticeably superior than that for a sample with uniformly distributed antidots: For high temperatures and low fields, the critical current is enhanced, whereas the region of thermomagnetic instabilities in the field-temperature diagram is significantly suppressed. These findings confirm the relevance of graded landscapes on the enhancement of pinning efficiency, as recently predicted by Misko and Nori [Phys. Rev. B 85, 184506 (2012)].
The superconducting critical current of corner-shaped Al superconducting microstrips has been investigated. We demonstrate that the sharp turns lead to asymmetric vortex dynamics, allowing for easier penetration from the inner concave angle than from the outer convex angle. This effect is evidenced by a rectification of the voltage signal otherwise absent in straight superconducting strips. At low magnetic fields, an enhancement of the critical current with increasing magnetic field is observed for a particular combination of field and current polarity, confirming a theoretically predicted competing interplay of superconducting screening currents and applied currents at the inner side of the turn.
5 May 2010 in Journal of Physics: Condensed Matter
We studied the structural, chemical and magnetic properties of non-doped ceria (CeO2) thin films electrodeposited on silicon substrates. Experimental results confirm that the observed room temperature ferromagnetism is driven by both cerium and oxygen vacancies. We investigated ceria films presenting vacancy concentrations well above the percolation limit. Irradiation experiments with neon ions were employed to generate highly oxygen defective CeO2 − δ structures. X-ray photoelectron spectroscopy and x-ray absorption near-edge structure spectroscopy were used to estimate the concentration of Ce3 + sites in the films, which can reach up to 50% of Ce3 + replacing Ce4 + , compared to a stoichiometric CeO2 structure. Despite the increment of structural disorder, we observe that the saturation magnetization continuously increases with Ce3 + concentration. Our experiments demonstrate that the ferromagnetism observed in ceria thin films, highly disordered and oxygen-deficient, preserving the fluorite-type structure only in a nanometer scale, remains intrinsically stable at room temperature.
The morphology of abrupt bursts of magnetic flux into superconducting films with engineered periodic pinning centers (antidots) has been investigated. Guided flux avalanches of thermomagnetic origin develop a treelike structure, with the main trunk perpendicular to the borders of the sample, while secondary branches follow well-defined directions determined by the geometrical details of the underlying periodic pinning landscape. Strikingly, we demonstrate that in a superconductor with relatively weak random pinning the morphology of such flux avalanches can be fully controlled by proper combinations of lattice symmetry and antidot geometry. Moreover, the resulting flux patterns can be reproduced, to the finest details, by simulations based on a phenomenological thermomagnetic model. In turn, this model can be used to predict such complex structures and to estimate physical variables of more difficult experimental access, such as the local values of temperature and electric field.