The Qiarbahete complex in NW China consists of gabbroic diorite, granodiorite, and late-stage quartz diorite porphyry veins. Zircon sensitive high-resolution ion microprobe (SHRIMP) U–Pb analyses show that the gabbroic diorite and granodiorite formed at 368 ± 5.2 Ma and 354 ± 4.1 Ma, respectively, indicating that the complex was emplaced in the Late Devonian–Early Carboniferous. The gabbroic diorites, characteristic of Sanukitoids, exhibit high Mg^# (62 average), MgO (6.84% average), Cr (195 ppm average), and Ni (61.4 ppm average) contents. The rocks show moderately fractionated rare earth element (REEs) patterns and weak negative Eu anomalies (δEu: 0.83–0.89), enrichment of large ion lithophile elements (LILEs), and depletion of high field strength elements (HFSEs), with low ϵ_Nd(t) values (1.46–1.73). The gabbroic diorites originated from partial melting of a hydrous mantle wedge followed by assimilation of crust during ascent. The granodiorites show a geochemical affinity with adakitic rocks, e.g. SiO₂ (64.95–67.87%) > 56%, Al₂O₃ (15.88–16.56%) > 15%, MgO (1.79–2.31%) < 3%, Sr (315–375 ppm) > 300 ppm, and Yb (1.84–2.06 ppm). They are enriched in light rare earth elements (LREEs) and LILEs and depleted in HFSEs, with weak negative Eu anomalies (δEu: 0.78–0.87). The granodiorites were mainly derived by the partial melting of a subducted oceanic slab, followed by subsequent melt–mantle interaction and crustal rocks contamination. All these indicate that the Qiarbahete complex was emplaced in a continental arc setting attending the southward subduction of the Junggar Ocean during the Late Devonian–early Carboniferous, generating the lateral accretion of continental crust in NW Tianshan.