This study develops a unified phenomenological creep model for polymer-bonded composite materials, allowing for predicting the creep behavior in the three creep stages, namely the primary, the secondary, and the tertiary stages under sustained compressive stresses. Creep testing is performed using material specimens under several conditions with a temperature range of 20 °C–50 °C and a compressive stress range of 15 MPa–25 MPa. The testing data reveal that the strain rate–time response exhibits the transient, steady, and unstable stages under each of the testing conditions. A rational function-based creep rate equation is proposed to describe the full creep behavior under each of the testing conditions. By further correlating the resulting model parameters with temperature and stress and developing a Larson–Miller parameter-based rupture time prediction model, a unified phenomenological model is established. An independent validation dataset and third-party testing data are used to verify the effectiveness and accuracy of the proposed model. The performance of the proposed model is compared with that of an existing reference model. The verification and comparison results show that the model can describe all the three stages of the creep process, and the proposed model outperforms the reference model by yielding 28.5% smaller root mean squared errors on average.

The influence of radiation-moisture aging on the thermodynamic and interface properties of nano-silica/silicone rubber (PDMS) composites was investigated using molecular dynamics simulation. The deterioration of polymer matrix was incorporated into the PDMS-silica interface models based on the hydrolysis products and the dominant role of cross-linking over chain scission. The results indicate that the long-chain structure with the higher molecular weight and the stronger intermolecular interactions are formed by incorporating multi-chain cross-linking and more hydroxyl groups. The coupling effects of the long-chain structure and stronger intermolecular interactions enhance the binding strength between the silica and PDMS matrix owing to the formation of more hydrogen bonds, and restrict the diffusion mobility of PDMS chains and water molecules. The aging of the PDMS matrix facilitates water molecules to adsorb on the surface of the silica and the PDMS matrix to form hydrogen bonds, and eventually weakens the bonding strength of the silica-PDMS interface.

The aging process is a common phenomenon in engineering, biological, and physical systems. The hazard rate function, which characterizes the aging process, is a fundamental quantity in the disciplines of reliability, failure, and risk analysis. However, it is difficult to determine the entire hazard function accurately with limited observation data when the degradation mechanism is not fully understood. Inspired by the seminal work pioneered by Jaynes [ Phys. Rev. 106, 620 (1956)], this study develops an approach based on the principle of maximum entropy. In particular, the time-dependent hazard rate function can be established using limited observation data in a rational manner. It is shown that the developed approach is capable of constructing and interpreting many typical hazard rate curves observed in practice, such as the bathtub curve, the upside down bathtub, and so on. The developed approach is applied to model a classical single function system and a numerical example is used to demonstrate the method. In addition its extension to a more general multifunction system is presented. Depending on the interaction between different functions of the system, two cases, namely reducible and irreducible, are discussed in detail. A multifunction electrical system is used for demonstration.

This study develops an engineering prediction model for stress relaxation of polymer composites, allowing the prediction of stress relaxation behaviour under a constant strain, over a range of temperatures. The model is based on the basic assumption that in the stress relaxation process the reversible strain is transformed to irreversible strain continuously. A strain-hardening model is proposed to incorporate nonlinear elastic behaviour, and a creep rate model is used to describe the irreversible deformation in the process. By using stress relaxation data at different temperatures, under different strains, the dependence on temperature and initial strain of the model parameters can be established. The effectiveness of the proposed model is verified and validated using three polymer composite materials. The performance of the model is compared with three commonly used stress relaxation models such as the parallel Maxwell and Prony series models. To ease the use of the proposed model in realistic structural problems, a user subroutine is developed, and the stress relaxation of a plate structure example is demonstrated.