Among the various forms of natural energies, heat is the most prevalent and least harvested energy. Scavenging and detecting stray thermal energy for conversion into electrical energy can provide a cost-effective and reliable energy source for modern electrical appliances and sensor applications. Along with this, flexible devices have attracted considerable attention in scientific and industrial communities as wearable and implantable harvesters in addition to traditional thermal sensor applications. This review mainly discusses thermal energy conversion through pyroelectric phenomena in various lead-free as well as lead-based ceramics and polymers for flexible pyroelectric energy harvesting and sensor applications. The corresponding thermodynamic heat cycles and figures of merit of the pyroelectric materials for energy harvesting and heat sensing applications are also briefly discussed. Moreover, this study provides guidance on designing pyroelectric materials for flexible pyroelectric and hybrid energy harvesting.

The electrocaloric effect (ECE), which refers to changes in the temperature of a material when an electric field is applied to or removed from the material, is one of the key phenomena of future highly efficient solid-state refrigeration devices.

Nanosized ZnO particles have been synthesized on cellulose nanofiber and boron nitride nanotube surfaces via a hydrothermal route to give a ternary nanostructure and explored flexible papers for the electrochemical and piezoelectric performance.

The strain-driven interfacial coupling between the ferromagnetic and ferroelectric constituents of magnetoelectric (ME) composites makes them potential candidates for novel multifunctional devices. ME composites in the form of thin-film heterostructures show promising applications in miniaturized ME devices. This article reports the recent advancement in ME thin-film devices, such as highly sensitive magnetic field sensors, ME antennas, integrated tunable ME inductors, and ME band-pass filters, is discussed. (Pb_1−xZr_x)TiO₃ (PZT), Pb(Mg_1/3Nb_2/3)O₃-PbTiO₃ (PMN-PT), Aluminium nitride (AlN), and Al_1−xSc_xN are the most commonly used piezoelectric constituents, whereas FeGa, FeGaB, FeCo, FeCoB, and Metglas (FeCoSiB alloy) are the most commonly used magnetostrictive constituents in the thin film ME devices. The ME field sensors offer a limit of detection in the fT/Hz^1/2 range at the mechanical resonance frequency. However, below resonance, different frequency conversion techniques with AC magnetic or electric fields or the delta-E effect are used. Noise floors of 1–100 pT/Hz^1/2 at 1 Hz were obtained. Acoustically actuated nanomechanical ME antennas operating at a very-high frequency as well as ultra-high frequency (0.1–3 GHz) range, were introduced. The ME antennas were successfully miniaturized by a few orders smaller in size compared to the state-of-the-art conventional antennas. The designed antennas exhibit potential application in biomedical devices and wearable antennas. Integrated tunable inductors and band-pass filters tuned by electric and magnetic field with a wide operating frequency range are also discussed along with miniaturized ME energy harvesters.