Geochemical anomalies play an important role in mineral exploration, because they are closely related to the formation of ore deposits. In this paper, the Au in the geochemical samples of 1:50,000 stream sediments in the Gouli exploration area, Qinghai Province, is selected as an example. The cumulative frequency method, local singularity analysis, and exploration data analysis method are used to process the Au data and determine the abnormal thresholds. Robust principal component analysis is used to explore the elemental associations. Among them, the effect of local singularity analysis is the best and it delineates the weak geochemical anomalies not delineated by cumulative frequency method and exploration data analysis method, which shows its superiority. Robust principal component analysis shows that Sb, W, and As are closely related to Au mineralization. Three anomalous areas are delineated in the Gouli exploration area. Gold ore-body is found to occur within anomaly area I. The other anomalous areas are highly consistent with abnormal elemental composition of Sb, W, and As. Moreover, these two areas are extremely conformable with the high-value areas determined by the binary state method. The optimality of the three methods are compared comprehensively, it is pointed out that it is more reasonable to use the local singularity analysis to determine the abnormal threshold. The anomaly areas II and III of Au determined by local singularity analysis have shown great potential for prospecting.

The Longquanzhan deposit is one of the largest gold deposits in the Yi-Shu fault zone (central section of the Tan-Lu fault zone) in Shandong Province, China. It is an altered-rock type gold deposit in which ore bodies mainly occur at the contact zone between the overlying Cretaceous rocks and the underlying Neoarchean gneissic monzogranite. Shi et al. reported that this deposit formed at 96 ± 2 Ma using pyrite Rb–Sr dating method and represents a new gold mineralization event in the Shandong Province in 2014. In this paper, we present new He–Ar–S isotopic compositions to further decipher the sources of fluids responsible for the Longquanzhan gold mineralization. The results show that the δ³⁴S values of pyrites vary between 0.9‰ and 4.4‰ with an average of 2.3‰. Inclusion-trapped fluids in ore sulfides have ³He/⁴He and ⁴⁰Ar/³⁶Ar ratios of 0.14–0.78 Ra and 482–1811, respectively. These isotopic data indicate that the ore fluids are derived from a magmatic source, which is dominated by crustal components with minor mantle contribution. Air-saturated water may be also involved in the hydrothermal system during the magmatic fluids ascending or at the shallow deposit site. We suggest that the crust-mantle mixing signature of the Longquanzhan gold deposit is genetically related to the Late Cretaceous lithospheric thinning along the Tan-Lu fault zone, which triggers constantly uplifting of the asthenosphere surface and persistent ascending of the isotherm plane to form the gold mineralization-related crustal level magma sources. This genetic model can be applied, to some extent, to explain the ore genesis of other deposits near or within the Tan-Lu fault belt.