Particulate fouling is a common fouling in heat exchange equipment, it causes tube corrosion and increases flow resistance. Particulate fouling increases the hidden danger of equipment and requires high treatment costs. In this paper, a novel Ni−P−TiO2 composite coating is prepared on 316 stainless steel using electroless plating and the fouling inhibition characteristics of the novel composite coating are studied using a dynamic monitoring experimental system. The experimental results show that the fouling thermal resistance of the Ni−P−TiO2 composite coating is obviously lower than that of 316 stainless steel under the same working conditions. With the increase in cooling water velocity and inlet temperature, the surface fouling thermal resistance decreases, while, with the increase in particle concentration, the fouling thermal resistance increases. Based on DLVO theory, it is found that the surface energy of Ni−P−TiO2 composite coating is close to the best surface energy for inhibiting particulate fouling deposition, which can significantly inhibit particulate fouling deposition. Compared with the stainless-steel surface of a conventional plate heat exchanger, the Ni−P−TiO2 composite coating not only inhibits the accumulation of particulate fouling, but also reduces the adhesion strength of particulate fouling; additionally, the fouling is easier to strip off the heat exchange surface, which realizes the lasting and efficient fouling inhibition on the heat exchange surface. The research results can provide a data reference for the fouling inhibition design and daily efficient operation of heat exchangers.
To reduce the impact of renewable energy generation on power grid stability, preheating combustion technology is introduced to maintain coal-fired boiler efficiency at low loads. A 330 MW coal-fired boiler is retrofitted with preheating combustion devices to improve combustion performance and lower NOx emissions. The device is installed in the reduction zone between the furnace burnout zone and the burner zone. The combustion characteristics of the boiler with and without these devices are examined at 50% rated load. Numerical simulations are conducted to analyze the effects of preheating coal input and burner arrangement on temperature and species distribution within the boiler. Results show that increasing preheating coal input from 0 to 30 t/h enhances NOx reduction due to a higher flow rate of preheated products. At a preheating coal input of 20 t/h, the combustion efficiency reaches 96.9%. The NOx concentration at the furnace exit rises from 122.4 to 171.3 mg/Nm3 as the height of the burner arrangement increases. The middle three-layer burner arrangement achieves a uniform temperature distribution and a peak combustion efficiency of 97.6%. The bottom and middle three-layer burner arrangements are recommended for efficient and clean combustion. Compared to the original boiler, the retrofitted boiler’s combustion efficiency increases from 96.3% to a maximum of 97.6%, while the NOx concentration at the furnace outlet drops from 168.1 to 93.2 mg/Nm3, showing that installing preheating combustion devices promotes efficient and clean combustion.
Biofouling on heat exchange devices can decrease heat transfer efficiency, corrode materials, and even lead to safety accidents. Most heat exchange devices are made of carbon steel that efficiently produces biofouling. However, in this paper, a nickel–phosphorus–reduced graphene oxide (Ni–P–rGO) coating was prepared on carbon steel by electroless plating to investigate the properties of iron bacteria biofouling. The surface coating was analyzed via scanning electron microscopy and Raman spectroscopy. After the carbon steel and the Ni–P–rGO coating were immersed into an iron bacteria solution for 120 h, the weight of the iron bacteria biofouling on the Ni–P–rGO coating sharply decreased when compared with the carbon steel. We can conclude that the concentration of graphene can affect the weight of iron bacteria biofouling. We also found that the coating solution with 40 mg/L of graphene performed the best in inhibiting biofouling by decreasing the weight of the biofouling by 97.2% compared to carbon steel.
Biofouling on heat exchange devices can decrease heat transfer efficiency, corrode materials, and even lead safety accidents. Most heat exchange devices are made of carbon steel, which produces biofouling easily. In this paper, nickel-phosphorus-reduced graphene oxide (Ni-P-rGO) coating was prepared on carbon steel by electroless plating as a kind of advanced material to study the properties of iron bacteria biofouling under flowing conditions. The coating was analyzed via scanning electron microscopy and Raman spectroscopy. The properties of iron bacteria biofouling on carbon steel and Ni-P-rGO coating were then compared under flowing conditions. Compared with carbon steel, the asymptotic value of fouling resistance on the Ni-P-rGO coating significantly decreased. Additionally, the induction period and the time of reaching the asymptotic value greatly increased. The inhibition properties of biofouling of advanced materials Ni-P-rGO coating under different temperatures, flow velocities, and initial concentrations was also studied.
With the rapid development of renewable energy sources in power generation, utility boilers need to perform load regulation over a wide range to maintain the stability of the power supply system. Preheating combustion technology is a potential approach to achieve wide load range operation, improve combustion stability, and lower NOx emissions from utility boilers. Preheating combustion devices (PCDs) were designed and installed in the reduction zone of a boiler. These devices preheated the coal at an excess air ratio ranging from 0.35 to 0.7 to generate high-temperature gas and char, which effectively reduced NOx formation in the furnace. Numerical studies were conducted to evaluate the combustion performance and nitrogen oxides emissions of a 330 MW utility boiler retrofitted with PCDs at different loads. The simulations were conducted over a load range of 20% to 100% of the rated load, corresponding to an electrical power of 66 MW to 330 MW. The preheated combustion device’s previous experimental data served as the boundary conditions of the preheated product nozzles. The simulation results demonstrated that the retrofitted boiler could operate stably from 20% to 100% of the rated load, maintaining acceptable combustion efficiency and lower NOx emissions. The combustion efficiency gradually dropped with decreasing boiler load, reaching a minimum value of 95.6%. As the load declined, the size of the imaginary tangent circle of the boiler shrank, while the ignition distance increased. Additionally, the variation in NOx concentration with load was complex. The NOx concentration at the furnace outlet was between 102.7 and 220.3 mg/m3, and the preheated products effectively reduced the nitrogen oxides produced by combustion in the furnace at all loads.