Through an ion exchange method, the composite 1⊃HPTS was prepared via the introduction of HPTS (8-hydroxy-1,3,6-pyrenetrisulfonicacid trisodium salt) into the channels of the compound [Zn(TIPA)(NO3−)2(H2O)]·5H2O (1). 1⊃HPTS exhibits durable dual-emission performance of both blue and yellow-green emission, and could act as a two-signal platform in aqueous solution. 1⊃HPTS exhibits ultrahigh sensitive response to a wide range of nitro-compounds, including nitroaromatics, aliphatic nitro-explosives and nitro-containing antibiotics. Particularly, 1⊃HPTS displays ratiometric fluorescence response against RDX. To the best of our knowledge, this is the first MOF-based probe with such an effect for the identification of RDX among luminescent materials. Moreover, the film based on the 1⊃HPTS sample shows high sensitivity towards 4-TNP vapor with good reusability. We also demonstrated that the detection of nitro-compounds using 1⊃HPTS predominantly involved photo-induced electron transfer and fluorescence resonance energy transfer.
Hollow SnO 2 nanospheres with oxygen vacancies simultaneously wrapped by a nitrogen-doped graphene network (SnO 2−x /N-rGO) improve the electrochemical performance of LIBs.
An ‘ion reservoir’, from an internal electric field and lower Li + /Na + adsorption energies at an anatase/TiO 2 (B) interface, ameliorated Li + /Na + storage.
Recent advances and perspectives in utilizing various supports to maximize the HER performance of Pt species are reviewed, along with the strategies for tailoring supports and future challenges and opportunities for regulating supports.