Three-dimensional (3D) printing technology is becoming a promising method for fabricating highly complex ceramics owing to the arbitrary design and the infinite combination of materials. Insufficient density is one of the main problems with 3D printed ceramics, but concentrated descriptions of making dense ceramics are scarce. This review specifically introduces the principles of the four 3D printing technologies and focuses on the parameters of each technology that affect the densification of 3D printed ceramics, such as the performance of raw materials and the interaction between energy and materials. The technical challenges and suggestions about how to achieve higher ceramic density are presented subsequently. The goal of the presented work is to comprehend the roles of critical parameters in the subsequent 3D printing process to prepare dense ceramics that can meet the practical applications.

Geopolymer is a porous inorganic material with a three-dimensional mesh structure, good mechanical properties, a simple preparation process (no sintering) and a low economic cost, and it is environmentally friendly. Geopolymer concrete has been widely used in the construction field, and many other studies have revealed that geopolymer will become one of the most promising inorganic materials with unique structure and properties. This paper provides a review of the development and current status of geopolymers and briefly explains the effects of material proportioning, experimental factors and activators on geopolymer performance. Because of the advantages of high specific surface area and high porosity, geopolymers could be used as adsorbent materials. This paper summarizes the research progresses of the adsorption of metal cations, anions, dyes, and gases by geopolymers, which emphasizes the geopolymer membranes in adsorption, and discusses the challenges and opportunities for the development of more efficient, sustainable and practical adsorption protocols.

Sodium-ion batteries have attracted worldwide attention as potential alternatives for large scale stationary energy storage due to the rich reserves and low cost of sodium resources. However, the practical application of sodium-ion batteries is restricted by unsatisfying capacity and poor rate capability. Herein, a novel mechanism of improving both interfacial and surface charge transfer is proposed by fabricating a graphene oxide/SnO₂/Co₃O₄ nanocomposite through a simple hydrothermal method. The formation of heterostructures between ultrafine SnO₂ and Co₃O₄ could enhance the charge transfer of interfaces owing to the internal electric field. The pseudocapacitive effect, which is led by the high specific area and the existence of ultrafine nanoparticles, takes on a feature of fast faradaic surface charge-transfer. Benefiting from the synergistic advantages of the heterostructures and the pseudocapacitive effect, the as-prepared graphene oxide/SnO₂/Co₃O₄ anode achieved a high reversible capacity of 461 mA h g⁻¹ after 80 cycles at a current density of 0.1 A g⁻¹. Additionally, at a high current density of 1 A g⁻¹, a high reversible capacity of 241 mA h g⁻¹ after 500 cycles is obtained. A full cell coupled by the as-prepared graphene oxide/SnO₂/Co₃O₄ anode and the Na₃V₂(PO₄)₃ cathode was also constructed, which exhibited a reversible capacity of 310.3 mA h g⁻¹ after 100 cycles at a current density of 1 A g⁻¹. This method of improving both interfacial and surface charge transfer may pave the way for the development of high performance sodium-ion batteries.