In order to control the cyanobacterial blooms in eutrophic water, an Ag/AgCl@ZIF-8 floating coating was prepared by a dip-coating method with a sponge, innovatively employed as a carrier for the removal of algae in natural water samples. The as-prepared photocatalyst was characterized by X-ray diffraction (XRD) and field emission scanning electron microscopy (SEM). The effects of this Ag/AgCl@ZIF-8 coating on algal removal and phytoplankton community structure in natural water samples with cyanobacterial blooms were investigated under sunlight. Results showed that Ag/AgCl@ZIF-8 distributed uniformly on the surface of the coating with good stability and algae removal efficiency in water bodies. After 6 h of exposure under sunlight, the chlorophyll a in the natural water samples was degraded by 99.9%, the densities of Microcystis aeruginosa were reduced by 92.6% and the densities and biomass of the other algae decreased by about 80%. Meanwhile, the content of colored dissolved organic matter (CDOM) in the samples was decreased, effectively controlling the cyanobacterial blooms. It was found that O₂^•− played the main role in the photocatalytic inactivation. In conclusion, the Ag/AgCl@ZIF-8 coating has a promising application potential for the removal of harmful cyanobacteria, and provides a new idea for the control of cyanobacterial blooms in water bodies.

In this study, a novel nanomaterial Cu₂O/SiO₂ was synthesized based on nano-SiO₂, and the inhibitory effects of different concentrations of Cu₂O/SiO₂ on the growth of Microcystis aeruginosa (M. aeruginosa) were studied. At the same time, the mechanism of Cu₂O/SiO₂ inhibiting the growth of M. aeruginosa was discussed from the aspects of Cu²⁺ release, chlorophyll a destruction, oxidative damage, total protein, and the phycobiliprotein of algae cells. The results showed that low doses of Cu₂O/SiO₂ could promote the growth of M. aeruginosa. When the concentration of Cu₂O/SiO₂ reached 10 mg/L, it exhibited the best inhibitory effect on M. aeruginosa, and the relative inhibition rate reached 294% at 120 h. In terms of the algae inhibition mechanism, Cu₂O/SiO₂ will release Cu²⁺ in the solution and induce metal toxicity to algae cells. At the same time, M. aeruginosa might suffer oxidative damage by the free radicals, such as hydroxyl radicals released from Cu₂O/SiO₂, affecting the physiological characteristics of algae cells. Moreover, after the addition of Cu₂O/SiO₂, a decrease in the content of chlorophyll a, total soluble protein, and phycobiliprotein was found, which eventually led to the death of M. aeruginosa. Therefore, Cu₂O/SiO₂ can be used as an algaecide inhibitor for controlling harmful cyanobacteria blooms.