Organic cathode materials have been demonstrated to be highly promising sustainable cathode materials for rechargeable lithium-ion batteries. However, the low redox potentials, low electrical conductivity, and the undesirable dissolution in organic electrolytes greatly limit their applications. Herein, two insoluble hypercrosslinked porous conductive polymers with phenothiazine motifs, HPEPT and HPPT, were successfully accomplished with high and stable discharge potentials at 3.65 and 3.48 V versus Li/Li+. HPEPT and HPPT with good electrical conductivity exhibited outstanding rate capabilities (up to 800 mA g−1) even at a high mass loading up to 70 wt%. This study shows that excellent organic cathode materials could be achieved readily through this prudent design.
Accurate measurement of overvoltage in power grids is of great significance to study the characteristics of overvoltage and design of insulation coordination. Based on the research of D-dot voltage sensor, we designed a Dual-Differential D-dot overvoltage sensor. In order to quantify the structural parameters of the sensor, improve the performance and measurement accuracy of the sensor. The Field-Circuit Coupling method was proposed to be used in the parameter design of D-dot overvoltage sensor. The joint simulation of space electromagnetic field model and equivalent circuit model of the Dual-Differential D-dot overvoltage sensor was established with the finite element simulation software Ansoft Maxwell and circuit simulation software Simplorer. Finally, the actual sensor was manufactured. A test platform was built to verify the steady-state and transient performance of the sensor. The results show that the Dual-Differential D-dot sensor has excellent steady-state and transient performance, the error of phase and amplitude are small, and the sensor can achieve the non-contact measurement of power transmission line. Simultaneously, the rationality of the Field-Circuit Coupling method was further verified.
1 May 2008 in Chinese Journal of Analytical Chemistry
Currently there are two non-contact measurement methods of the transmission line voltage based on field sensor: One is calculation with inverse problem of electric field for solution, and the other is to solve by numerical integration algorithm. In general, the first one is confronted with data equation solving problems and difficulties in accurate calibration as well as low precision, while the second one is troubled by the complexity of algorithm equation and unsatisfactory integration node, etc. In view of the above problems, this paper improves on the basis of Gaussian integral algorithm to seek better nodes, in order to reduce the difficulty of solving and improve the measurement accuracy of the integral algorithm. Firstly, starting from the Gaussian integral algorithm, and making a research to improve Gaussian integral algorithm theory. Then, the finite element simulation of three-phase transmission line through Maxwell software is built and the space electric field distribution data is acquired to calculate integral node as well as its corresponding weights. Finally, the three-phase transmission line voltage measurement test platform with D-dot sensor voltage meas-urement system is built to test verification. The text results show that the voltage measurement method based on the improved Gaussian Integral has characteristics of simple solution, better integral node and higher precision, and all the measured voltage errors are less than 0.45%.