This first study investigated the presence of dioxins and furans in river sediments around a craft village in Vietnam, focusing on Secondary Steel Recycling. Sediment samples were collected from various locations along the riverbed near the Da Hoi Secondary Steel Recycling village in Bac Ninh province. The analysis was conducted using a HRGC/HRMS-DFS device, detecting a total of 17 dioxin/furan isomers in all samples, with an average total concentration of 288.86 ng/kg d.w. The concentrations of dioxin/furan congeners showed minimal variation among sediment samples, ranging from 253.9 to 344.2 ng/kg d.w. The predominant compounds in the dioxin group were OCDD, while in the furan group, they were 1,2,3,4,6,7,8-HpCDF and OCDF. The chlorine content in the molecule appeared to be closely related to the concentration of dioxins and their percentage distribution. However, the levels of furan isomers did not vary significantly. The distribution of these compounds was not dependent on the flow direction, as they were mainly found in solid waste and are not water-soluble. Although the hepta and octa congeners had high concentrations, when converted to TEQ values, the tetra and penta groups (for dioxins) and the penta and hexa groups (for furans) contributed more to toxicity. Furthermore, the source of dioxins in sediments at Da Hoi does not only originate from steel recycling production activities but also from other combustion sites. The average total toxicity was 10.92 ng TEQ/kg d.w, ranging from 4.99 to 17.88 ng TEQ/kg d.w, which did not exceed the threshold specified in QCVN 43:2017/BTNMT, the National Technical Regulation on Sediment Quality. Nonetheless, these levels are still concerning. The presence of these toxic substances not only impacts aquatic organisms in the sampled water environment but also poses potential health risks to residents living nearby.

Environmental monitoring is essential to assess and, if possible, anticipate the consequences of various marine economic developments. This study describes progress in environmental monitoring by developing and applying a eutrophication index (EI) for marine protected areas (MPAs). The EI combines available data, such as biological oxygen demands, dissolved inorganic nitrogen and phosphorus, and chlorophyll-a, with the weighting factors calculated from principal component analysis to assess environmental quality. Its effectiveness was tested using nearly three decades of environmental data (since 1996) from the Nha Trang MPA in Vietnam. The EI revealed clear trends in environmental quality. In the period 1996–2006, environmental conditions deteriorated, negatively impacting aquaculture. In the later period, 2007–2024, improved environmental protection policies, technological developments, expanding tourism, and heightened public awareness contributed to a reversal of this trend. During the earlier period, the EI indicated poor environmental quality (Level V), while in the later years, it improved significantly, approaching Level II. This study also identified the spatial eutrophication patterns and helped to determine the causes of specific eutrophication levels. These included port development, aquaculture activities, and domestic waste discharge. These findings highlight the close relationship between environmental quality and economic activities in the bay. Overall, the new EI and its sensitivity maps enhance environmental monitoring capabilities. They provide valuable tools for decision-makers, aiding in the strategic planning of marine economic development, ecosystem protection, and sustainable resource use. The approach supports long-term environmental stewardship and more informed, adaptive management of coastal and marine areas.