Mainly acidic Stephanian to early Permian volcanic rocks and intercalated sediments accumulated in the Thuringian Forest Basin (TFB) in central Germany to a total thickness of ca. 2000 m. This basin offers a wide range of biostratigraphic information. New high-precision U–Pb CA–ID–TIMS (chemical abrasion–isotope dilution–thermal ionization mass spectrometry) zircon data are obtained from volcanic rocks for the first time in the TFB. Pre-treatment of the zircons by chemical abrasion was important to get rid of severe Pb loss. The zircon ages of the investigated formations indicate that the total duration of the volcanic activity in the TFB was considerably shorter [ca. 4 Myr: from 300 Ma for the oldest formation (Möhrenbach) until ca. 296 Ma for the youngest volcanic-rock-bearing formation (Rotterode)] than suggested in previous studies (ca. 20 Myr; 295 Ma to 275 Ma). Consequently, the well-documented gap of the sedimentary record from the early Permian volcanic rocks up to the Illawarra geomagnetic reversal has to be extended to ca. 25 Myr from the previously proposed 5 Myr. The zircon ages of the investigated volcanic rocks allow the constraining of some intercalated fossiliferous horizons crucial for biostratigraphic correlation of latest Carboniferous–early Permian (Rotliegend) sections. The high-precision age data require a new interpretation of the evolution of the TFB but also offer the chance to obtain a more reliable comparison of the timing of the main magmatic activity across intramontane basins as well as to obtain links to the Standard Global Stratigraphic Scale.

The Altenberg–Teplice Volcanic Complex (ATVC) is a large ~ NNW–SSE trending volcano-plutonic system in the southern part of the Eastern Erzgebirge (northern Bohemian Massif, south-eastern Germany and northern Czech Republic). This study presents high precision U–Pb CA-ID-TIMS zircon ages for the pre-caldera volcano-sedimentary Schönfeld–Altenberg Complex and various rocks of the caldera stage: the Teplice rhyolite, the microgranite ring dyke, and the Sayda-Berggießhübel dyke swarm. These data revealed a prolonged time gap of ca. 7–8 Myr between the pre-caldera stage (Schönfeld–Altenberg Complex) and the climactic caldera stage. The volcanic rocks of the Schönfeld–Altenberg Complex represent the earliest volcanic activity in the Erzgebirge and central Europe at ca. 322 Ma. The subsequent Teplice rhyolite was formed during a relatively short time interval of only 1–2 Myr (314–313 Ma). During the same time interval (314–313 Ma), the microgranite ring dyke intruded at the rim of the caldera structure. In addition, one dyke of the Sayda-Berggiesshübel dyke swarm was dated at ca. 314 Ma, while another yielded a younger age (ca. 311 Ma). These data confirm the close genetic and temporal relationship of the Teplice rhyolite, the microgranite ring dyke, and (at least part of) the Sayda-Berggießhübel dyke swarm. Remarkably, the caldera formation in the south of the Eastern Erzgebirge (caldera stage of ATVC: 314–313 Ma) and that in the north (Tharandt Forest caldera: 314–312 Ma) occurred during the same time. These data document a large ~ 60 km NNW–SSE trending magmatic system in the whole Eastern Erzgebirge. For the first time, Hf-O-isotope zircon data was acquired on the ring dyke from the ATVC rocks to better characterize its possible sources. The homogeneous Hf-O-isotope zircon data from the microgranite ring dyke require preceding homogenization of basement rocks. Some small-scale melts that were produced during Variscan amphibolite-facies metamorphism show similar Hf-O-isotope characteristics and can therefore be considered as the most probable source for the microgranite ring dyke melt. In addition, a second source with low oxygen isotope ratios (e.g. basic rocks) probably contributed to the melt and possibly triggered the climactic eruption of the Teplice rhyolite as well as the crystal-rich intrusion of the ring dyke.

We investigated physical, chemical and isotope (S, O) parameters of sulfate from acid mine drainage from the polymetallic sulfide ore deposit Freiberg (Germany), which was mined for more than eight hundred years. Two main groups of water were distinguished: 1. Flowing mine water with sulfate concentrations of less than 9000 mg/1 and pH values higher than 3.2 2. Pore water in weathered low grade ores and pools with sulfate concentrations higher than 9000 mg/1 and pH values below 3.2. The sulfur and oxygen isotope composition of sulfate from flowing mine waters reflects mixing of sulfate from two sulfur sources: a) atmospheric sulfur from precipitation and b) sulfate formed as a result of sulfide oxidation processes. Sulfur isotope values of mine water sulfate were used to estimate the contribution of sulfate derived through oxidation of sulfides. The sulfur isotope composition of pore water sulfate and precipitated sulfate (jarosite) from weathered low grade ore samples is identical to the sulfur isotope composition of primary sulfides. The oxygen isotope composition of pore water sulfate from low grade ore samples indicates that the oxidation process proceeds relatively slowly in O₂-depleted waters, probably without significant microbial catalysis.