In recent years, supercapacitors are attracting great attention as one kind of electrochemical energy storage device, which have a high power density, a high energy density, fast charging and discharging, and a long cycle life. As a solution processing method, printing technology is widely used to fabricate supercapacitors. Printable nanomaterials are critical to the fabrication of high-performance supercapacitors by printing technology. In this work, the advantages of printing technology are summarized. Moreover, various nanomaterials used to fabricate supercapacitors by printing technology are presented. Finally, the remaining challenges and broad research as well as application prospects in printing high-performance supercapacitors with nanomaterials are proposed.
Microstructures are playing an important role in manufacturing functional devices, due to their unique properties, such as wettability or flexibility. Recently, various microstructured surfaces have been fabricated to realize functional applications. To achieve the applications, photolithography or printing technology is utilized to produce the microstructures. However, these methods require preparing templates or masks, which are usually complex and expensive. Herein, a facile approach for fabricating microstructured surfaces was studied based on etched template by inkjet printing technology. Precured polydimethylsiloxane substrate was etched by inkjet printing water-soluble polyacrylic acid solution. Then, the polydimethylsiloxane substrate was cured and rinsed, which could be directly used as template for fabricating microstructured surfaces. Surfaces with raised dots, lines, and squares, were facilely obtained using the etched templates by inkjet printing technology. Furthermore, controllable anisotropic wettability was exhibited on the raised line microstructured surface. This work provides a flexible and scalable way to fabricate various microstructured surfaces. It would bring about excellent performance, which could find numerous applications in optoelectronic devices, biological chips, microreactors, wearable products, and related fields.
The relationship between the structure of peptides LR5 (LHKFR) and YR6 (YGLYPR) and their antioxidant and anti-inflammatory activity remains unclear. Herein, leucine, tyrosine, proline, and phenylalanine at different positions in the peptides were replaced by Alanine (Ala), and two new pentapeptides (AR5 and LAR5) and four hexapeptides (AGR6, YAR6, YLR6, and YGR6) were obtained. The effect of Ala replacement on the hydrophobicity, cytotoxicity, NO inhibition rate, and active oxygen radical scavenging ability of these peptides and their antioxidant and anti-inflammatory abilities were investigated. The results indicated that the hydrophobicity of the peptides was associated with their amino acid composition and their specific sequence. However, hydrophobicity had no significant effect on cytotoxicity. Ala replacement was shown to enhance hydrophobicity and consequently increased the antioxidant and anti-inflammatory activity of the peptides. The molecular docking studies indicated that the amino acid interactions of the peptide with the Keap1 protein influenced the hydrophobicity and thus affected the antioxidant activity of the peptide.
In this paper, carboxymethyl cellulose was used as matrix and graphene was used as conductive filler, compounding graphene with carboxymethyl cellulose. To prepare graphene/cellulose composite conductive film, the composite effect of it was discussed. Firstly, graphene was prepared by chemically reducing graphene oxide with ascorbic acid as reducing agent, and its conductivity was up to 110.2 S/cm. And then, graphene and carboxymethyl cellulose were composited by physical blending. When the mass ratio of graphene oxide to carboxymethyl cellulose was GO:CMC=1:6, the electrical conductivity of the composite film was 8.5×10-2 S/cm. Finally, graphene/cellulose composite conductive film was prepared by coating a graphene/cellulose composite system on a polytetrafluoroethylene substrate.