Ceramic coating is an effective method for improving the erosion resistance of a material, particularly for titanium alloys. In this study, a TiN/ZrN (ceramic/ceramic) nanoscale multilayer coating is designed and prepared on the Ti6Al4V titanium alloy surface by the physical vapor deposition (PVD) process. The cross-sectional microstructure and phase composition are measured using SEM and XRD, respectively. The hardness, elastic modulus, and adhesion of the coating are measured by the nano-indentation and scratch method. The erosion test is conducted at a 45° angle with 100 m/s velocity using self-developed erosion equipment. The erosion resistance mechanisms of both the substrate and the coating are revealed more intuitively through a single sand particle impact test. The results show that the erosion resistance rate of the coating is 15.5 times higher than that of the titanium alloy substrate. The damage mechanisms of material removal of the coating include crack deflection, crack branching, and succeeding interaction between them when suffering an impacting load. These cracks are started from the droplets and the stress concentrations on the coating surface during the preparation of coating. They are the primary reasons for the decrease in the erosion resistance of the coating. This research is important for the optimization of the erosion-resistant coating structure.

TiN/ZrN multilayers can effectively improve the erosion resistance of metals, particularly titanium alloys employed in aero engines. To explore the corrosion damage mechanism of TiN/ZrN nanoscale multilayers (nanolaminate), a novel [TiN/ZrN]₁₀₀ nanolaminate coating was deposited on Ti-6Al-4V alloys by multi-arc ion plating method. Salt spray corrosion tests and hot corrosion experiment were carried out to evaluate the corrosion resistance of the coating. The corrosion and damage mechanisms were explored with the help of detailed microstructure, phase composition and element distribution characterizations. The salt spray corrosion tests showed that the [TiN/ZrN]₁₀₀ nanolaminate coating possessed good corrosion resistance, which protected substrate against the corrosion. The low temperature hot corrosion tests showed that the oxidation occurred on the surface of the coating, which improved the oxidation resistance of the sample. However, the oxidized droplets squeezed the coating, and destroyed the oxidized layers. As a result, the coating was peeled off from the substrate. The research highlights the corrosion resistance of the novel TiN/ZrN nanolaminate coating and offers a support for their application in engine compressor blade.

TiN/Ti coatings have great application potential in improving aero-engine server lives in a dusty environment. However, the damage behavior and mechanism of the coating and substrate under high impact speed and multi-direction loading conditions has scarcely been investigated. In this paper, TiN/Ti coatings were deposited on Ti6Al4V alloys by a magnetic filter cathode vacuum arc. Multi-directional impact tests were carried out by a gas gun system at, 45°, 60°, and 90° with a velocity of 330 m/s. The damage behaviors and mechanisms of the TiN/Ti coatings were investigated and revealed by researching the damage morphology, crack propagation, and stress distribution. The results show that plastic deformation occurs both in the coatings and the substrates under high speed impacting. Cracks extend vertically downward in the TiN layer first and are deflected at the Ti layer when the driving force is not enough. Circular cracks and radical cracks are found to form network cracks on the surface of the coating and the shear stress loaded by the particles, which drives cracks’ propagation is the main reason for the peeling off on the coatings.