Nano-crystalline diamond has been extensively researched and applied in the fields of tribology, optics, quantum information and biomedicine. In virtue of its hardness, the highest in natural materials, diamond outperforms the other materials in terms of wear resistance. Compared to traditional single-crystalline and poly-crystalline diamonds, nano-crystalline diamond consists of disordered grains and thus possesses good toughness and self-sharpening. These merits render nano-crystalline diamonds to have great potential in tribology. Moreover, the re-nucleation of nano-crystalline diamond during preparation is beneficial to decreasing surface roughness due to its ultrafine grain size. Nano-crystalline diamond coatings can have a friction coefficient as low as single-crystal diamonds. This article briefly introduces the approaches to preparing nano-crystalline diamond materials and summarizes their applications in the field of tribology. Firstly, nano-crystalline diamond powders can be used as additives in both oil- and water-based lubricants to significantly enhance their anti-wear property. Nano-crystalline diamond coatings can also act as self-lubricating films when they are deposited on different substrates, exhibiting excellent performance in friction reduction and wear resistance. In addition, the research works related to the tribological applications of nano-crystalline diamond composites have also been reviewed in this paper.

Bi-composite surface texture configurations are proposed to study the friction performance of a mechanical seal under low speed. Three sets of comparative experiments were designed. They involved friction pairs with different pairing materials, single texture patterns, and bi-composite surface texture configurations. Tribological performances, such as friction coefficient, wear quantity, and surface topography, were measured. The research results showed that the average friction coefficient and surface temperature rise of the 3-C3 group (triangular texture in SSiC–conventional spiral groove in SSiC) were only 0.052 and 3.8 °C, respectively, which was the smallest friction coefficient and lowest temperature rise of all the test subjects. What’s more, the wear of M120D was mainly caused by the cutting effect of the texture edges, the adhesive wear of the non-textured areas, and the secondary wear caused by debris from the internal texture. It was indicated that the bi-composite patterns of spiral-triangle could produce a ‘synergistic effect’ by improving tribological performance and reaching lower friction in low-rotational-speed operation, which could provide a basis for designing a long-lasting and exceptionally reliable mechanical seal.

Diamond films prepared by chemical vapor deposition will exhibit different surface morphologies, which are determined by the texture and the structural perfection of the deposited diamond. In general, its surface morphology can be controlled by adjusting the deposition conditions. In the present work, textured diamond film was deposited on single crystalline silicon through pre-seeding by diamond nanosheets, rather than controlling the deposition conditions. The employed diamond nano-sheets were prepared by cleavage along a plane, exhibiting good crystallinity. Before chemical vapor deposition, the as-prepared diamond nano-sheets were pre-seeded on the surface of single crystalline silicon as nucleation sites for diamond growth. SEM and XRD results show that the prepared diamond films have a texture. FIB observation reveals that diamonds homogeneously grow on the pre-seeded diamond nano-sheets during chemical vapor deposition, achieving the diamond film with texture. Our work provides a new strategy to prepare textured diamond film.

In the present study, the tribological properties of diverse crystalline diamond coating with micro (MCD) and nanometer (NCD) sizes, fabricated by the microwave plasma chemical vapor deposition (MPCVD) method, are systematically investigated in dry and seawater environments, respectively. Owing to the SiO₂ lubricating film with extraordinary hydrophilicity performance by a tribochemical reaction, the average friction coefficient (COF) and wear rate of NCD coating under seawater decreased by 37.8% and 26.5%, respectively, comparing with in dry conditions. Furthermore, graphite would be generated with the increment of surface roughness. Graphite transformed from the diamond under high contact pressure. Thus, with the synergism between SiO₂ lubricating film with extraordinary hydrophilicity performance and graphite, the corresponding COF and wear rate of MCD would be further decreased by up to 64.1% and 39.5%. Meanwhile, various characterizations on morphology, spectra, and tribological performance of the deposited diamond coating were conducted to explore the in-depth mechanism of the enhanced tribological performance of our NCD and MCD coatings in the extreme under seawater working conditions. We envision this work would provide significant insights into the wear behavior of diamond coatings in seawater and broaden their applications in protective coatings for marine science.

In this study, a diamond/diamond-like carbon (DLC) composite coating was designed and fabricated utilizing a combination of chemical vapor deposition (CVD) and magnetron-sputtering-assisted ion beam deposition. This was designed to cope with severe problems such as high wear due to insufficient lubrication under dry sliding conditions with a single diamond. The tribological properties of the fabricated coatings under dry conditions were comparatively evaluated. The results demonstrate that the diamond/DLC composite coatings significantly enhance the tribological performance relative to their single-layer diamond counterparts. Specifically, a 33.73% reduction in the average friction coefficient and a 39.55% decrease in the average wear rate were observed with the MCD (microcrystalline diamond/DLC coating. Similarly, a 16.85% reduction in the average friction coefficient and a 9.69% decrease in the average wear rate were observed with the UNCD (ultrananocrystalline diamond)/DLC coating. Analysis of the worn track morphology and structure elucidated the underlying friction mechanism. It is proposed that the DLC top layer reduces the surface roughness of the underlying diamond coating and mitigates abrasive wear in the dry environment. Furthermore, the presence of the DLC film promotes graphitization via phase transition during sliding, which enhances lubricity and facilitates the establishment of a smooth friction interface.