Sulfur (S) has been considered as a promising cathode candidate for lithium batteries due to its high theoretical specific capacity and energy density. However, the low active material utilization, severe capacity fading, and short lifespan of the resultant lithium–sulfur (Li–S) batteries have greatly hindered their practicality. In this work, a multi-functional polyacrylonitrile/silica nanofiber membrane with an integral ultralight and thin multi-walled carbon nanotube sheet is presented and it provides a new approach to significantly improve the overall electrochemical performance of Li–S batteries. The experimental results are in agreement with molecular modeling studies based on density functional theory and Monte Carlo simulations. Remarkably, this design is favorable for the fast diffusion of both lithium ions and electrons and the mitigation of the diffusion of polysulfides. As a consequence, a high reversible capacity of 741 mA h g−1 at 0.2C after 100 cycles with excellent cyclability and high-rate performance (627 mA h g−1 at 1C) are achieved even with a high sulfur loading of 70 wt% in the cathode, revealing its great potential for energy storage applications. Moreover, a capacity of 426 mA h g−1 is retained after 300 cycles at a high current density of 2C. These results represent a major step forward in the progress of Li–S battery technologies.
We evaluate the performance of fiber Bragg grating (FBG) sensors for the measurement of dynamic strains in complex composite structures. The particular structure used in this study is an integrally stiffened composite panel for which the stiffeners and skin are fabricated in a single layup and cure process. Surface-mounted FBG sensors are bonded to the panels after curing, whereas embedded FBG sensors are successfully incorporated during the fabrication process. A finite element model was also constructed of the stiffened panel. The panels were subjected to repeated impacts and the post-impact vibration response of the panel was measured through the FBG sensor responses. Little change to the global response of the panel was observed after the repeated impacts, through the dynamic response of the surface-mounted FBGs. Pulsed phase thermography and micro-computer-tomography imaging of the panel confirmed that the damage was localized near the impact locations, producing negligible changes to the global response of the panel. All of the embedded FBG sensors survived the fabrication and multiple impacts; however, as these were embedded close to the neutral axis of the panel, they were not very sensitive to the vibration modes. Excitation of the panel near the first natural frequency did produce a measurable response in the FBG sensors, confirming their functionality.