The strong metal-support interaction (SMSI) in supported catalysts plays a dominant role in catalytic degradation, upgrading, and remanufacturing of environmental pollutants. Previous studies have shown that SMSI is crucial in supported catalysts' activity and stability. However, for redox reactions catalyzed in environmental catalysis, the enhancement mechanism of SMSI-induced oxygen vacancy and electron transfer needs to be clarified. Additionally, the precise control of SMSI interface sites remains to be fully understood. Here we provide a systematic review of SMSI's catalytic mechanisms and control strategies in purifying gaseous pollutants, treating organic wastewater, and valorizing biomass solid waste. We explore the adsorption and activation mechanisms of SMSI in redox reactions by examining interfacial electron transfer, interfacial oxygen vacancy, and interfacial acidic sites. Furthermore, we develop a precise regulation strategy of SMSI from systematical perspectives of interface effect, crystal facet effect, size effect, guest ion doping, and modification effect. Importantly, we point out the drawbacks and breakthrough directions for SMSI regulation in environmental catalysis, including partial encapsulation strategy, size optimization strategy, interface oxygen vacancy strategy, and multi-component strategy. This review article provides the potential applications of SMSI and offers guidance for its controlled regulation in environmental catalysis.

Vehicle emissions are regarded as an important contributor to urban air pollution in China and most previous studies focused on megacities. However, the vehicle pollution in middle-sized cities becomes more severe due to the increasing vehicle population (VP) and lagged control policy. This study takes Langfang, a typical middle-sized city bordered by two megacities (Beijing and Tianjin), as the target domain to investigate vehicle emissions. The speed correction curves (SCC) are introduced to improve the vehicle emission factors (EF) simulation in official technical guidelines on emission inventory (GEI). A multi-year vehicle emission inventory (from 2011 to 2025) is developed in Langfang. From 2011 to 2017, the total vehicle emissions in Langfang decrease for carbon monoxide (CO), but increase for volatile organic compounds (VOCs), nitrogen oxides (NOx), and inhalable particles (PM10), respectively. From 2018 to 2025, the emissions would increase more rapidly in Langfang than in Beijing and Tianjin, indicating the middle-sized cities may become a significant contributor to air pollution in China. Four possible control policies, including VP constrained (VPC), public transportation promotion (PTP), new energy vehicles promotion (NEP), and freight transportation structure optimization (FTO) are evaluated. The most significant emissions reductions are observed under the FTO for CO, NOx, and PM10, and under the VPC for VOCs. The spatial distributions of vehicle emissions show a high order of heterogeneity, indicating that local conditions should be considered in policy formulation in addition to national consistency. More comprehensive policies should be implemented to mitigate the vehicle pollution in middle-sized cities.