Combustible gases, such as CH₄ and CO, directly or indirectly affect the human body. Thus, leakage detection of combustible gases is essential for various industrial sites and daily life. Many types of gas sensors are used to identify these combustible gases, but since gas sensors generally have low selectivity among gases, coupling issues often arise which adversely affect gas detection accuracy. To solve this problem, we built a decoupling algorithm with different gas sensors using a machine learning algorithm. Commercially available semiconductor sensors were employed to detect CH₄ and CO, and then support vector machine (SVM) applied as a supervised learning algorithm for gas classification. We also introduced a pairing plot scheme to more effectively classify gas type. The proposed model classified CH₄ and CO gases 100% correctly at all levels above the minimum concentration the gas sensors could detect. Consequently, SVM with pairing plot is a memory efficient and promising method for more accurate gas classification.