Transparent conductive elastomers are an emerging platform for stretchable electronics, attractive due to their ability to sustain high physical deformations while still fulfilling optical/electrical functions. Poly(deep eutectic solvent)s (DESs) can serve as a new type of transparent conductive elastomers as a result of their low cost, green fabrication, non-toxicity and post-treatment-free advantages. Here, we report a 3D patternable (starfish type), transparent (transmittance of ∼81%), stretchable (strain up to 150%), and conductive (∼0.2 S m⁻¹) elastomer based on the photopolymerization of the acrylic-acid/choline-chloride DES. The combination of transparency, elasticity, conductivity and patternability allows the poly(DES) elastomers to serve as flexible tactile/strain sensors. Our methodology has the potential to exploit the new application of poly(DESs), and opens up a new powerful route to fabricate all-organic transparent, conductive elastomers for a myriad of applications in future flexible electronics.

Conductive elastomers (CEs) with strong mechanical properties have been fabricated and used in flexible electronics. However, the development of CEs with both super-high mechanical strength and extreme stretchability remains challenging. This paper reports on the development of a series of mechanically strong and tough CEs based on photopolymerizable deep eutectic solvents (PDESs) with dense hydrogen bonding interactions. One of these CEs exhibits the highest reported mechanical performance for elastomers, with tensile strength, strain at break and toughness up to 31.21 MPa, 3645% and 615 MJ m⁻³, respectively. Notably, this CE tolerates puncture and can lift a 10.5 kg weight (9500 times its own weight) without any failure. In addition, the series of CEs also shows excellent transparency (>94% in the visible range), favorable conductivity (0.007–0.04 S m⁻¹), tunable stretchability (strain from 22% to 6164%) and good self-healing capability (electrical healing efficiency of 99% within 0.26 s). In view of the comprehensive properties of the CEs, we demonstrate the practical suitability of CEs by including them in a strain sensor to detect human motion. Based on their extremely facile preparation process and practical functionalities, we believe that CEs will not only contribute new methods for the development of mechanically strong conductors, but also open up novel avenues for flexible electronics.

A new type of transparent conductive elastomer with excellent autonomous self-healing capability in harsh organic solvent environments is reported.