Transparent Ho2O3 ceramics are fabricated and their magneto-optical characteristics are reported for the first time, to the best of our knowledge. The value of the Verdet constant was measured in the 560–1064 nm wavelength range, and the value at 1064 nm is 46.3 rad/Tm. This corresponds to the Verdet constant for terbium aluminum garnet (TAG), which is ~1.3 times higher than that of terbium gallium garnet (TGG). The in-line transmittance at 1 μm wavelength is only ~60%, but the optical properties can be further improved by optimizing sintering conditions. This is a new potential magneto-optic material that can be applicable for high-average-power lasers.
The thermal-birefringence-induced depolarization in terbium gallium garnet (TGG) ceramics has been investigated experimentally. The depolarization ratio of has been observed at the maximum input power of 117 W cw, which corresponds to a normalized laser power of . As predicted by the previously proposed theory, the amount of depolarization ratio and its slope with respect to the laser power of the ceramic TGG was approximately the same as that previously reported for high-quality-cut single crystal.
Transparent polycrystalline ceramics with cubic crystal structure have played important roles in a wide variety of solid-state laser applications, whereas for non-cubic structures, single crystal only has been used. For further progress in optical technologies, effective materials beyond the current limitations are necessary. Here we report a new type of non-cubic ceramic laser material that overturns conventional common sense. It is hexagonal Nd-doped fluorapatite (Nd:FAP) ceramics with an optical quality comparable to single crystal while having random crystal orientation. It is composed of ultrafine grains with a loss coefficient of 0.18 cm−1 at a lasing wavelength of 1063 nm, and its laser oscillation was demonstrated. This is the first verification of lasing in randomly oriented non-cubic ceramics. Laser oscillation in the non-cubic ceramics was realized through both advanced liquid-phase nano-powder synthesis technology and highly controlled pulsed-current sintering techniques. Our findings should open new avenues for future solid-state laser and optical applications.
An efficient high-power laser operation has been demonstrated by using a cryogenic Yb:YAG composite ceramic with a total-reflection active-mirror arrangement. The composite ceramic, which had no high-reflection coating and was cooled with liquid nitrogen directly, showed four-level operation even at of high pump density. A cw output power was obtained with 65% optical efficiency and 72% slope efficiency.
The temperature dependence of the Verdet constant of a 0.8 at % Ti-doped terbium aluminum garnet (TAG) ceramics was investigated using lasers with wavelengths of 632.8 and 1064 nm. A high value of the Verdet constant was obtained at 296 K – namely, 184 and 53 rad/Tm for 632.8 and 1064 nm, respectively. The Verdet constant of the Ti:TAG ceramics at 1064 nm is about 1.5 times higher than that of the terbium gallium garnet (TGG) ceramics. The transmittance of this sample was about 75% at the wavelength of 1 μm. This material represents a possible candidate for next-generation devices that utilize the magneto-optic effect.
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