The transformation from combustion-based to renewable energy technologies is of paramount importance due to the rapid depletion of fossil fuels and the dramatic increase in atmospheric CO₂ levels resulting from growing global energy demands. To achieve the Paris Agreement's long-term goal of carbon neutrality by 2050, the full implementation of clean and sustainable energy sources is essential. Consequently, there is an urgent demand for zero or low-carbon fuels with high energy density that can produce electricity and heat, power vehicles, and support global trade. This review presents the global motivation to reduce carbon dioxide by utilizing hydrogen technology, which is key to meeting future energy demands. It discusses the basic properties of hydrogen and its application in both prototype and large-scale efficient technologies. Hydrogen is a clean fuel and a versatile energy carrier; when used in fuel cells or combustion devices, the final product is water vapor. Hydrogen gas production methods are reviewed across renewable and non-renewable sources, with reaction processes categorized as green, blue, grey, black, pink, and turquoise, depending on the reaction pathway and CO₂ emissions management. This review covers the applications of hydrogen technology in petroleum refining, chemical and metrological production, hydrogen fuel cell electric vehicles (HFCEVs), backup power generation, and its use in transportation, space, and aeronautics. It assesses physical and material-based hydrogen storage methods, evaluating their feasibility, performance, and safety, and comparing HFCEVs with battery and gasoline vehicles from environmental and economic perspectives. Finally, the prospects and challenges associated with hydrogen production, handling, storage, transportation, and safety are also discussed.

Yttria-stabilized zirconia (YSZ) is the most common electrolyte material for solid oxide fuel cells. Herein, we conducted a comparative study on the densification behavior of three different kinds of commercial 8 mol% YSZ powders: (i) TZ-8Y (Tosoh, Japan), (ii) MELox 8Y (MEL Chemicals, UK), and (iii) YSZ-HT (Huatsing Power, China). The comparison was made on both the self- supporting pellets and thin-film electrolytes coated onto a NiO–YSZ anode support. For the pellets, MELox 8Y showed the highest densification at lower sintering temperatures with 93% and 96% of the theoretical density at 1250 and 1300 °C, respectively. Although YSZ-HT showed a higher sintering rate than TZ-8Y, a sintering temperature of 1350 °C was required for both the powders to reach 95% of the theoretical density. For the thin-film electrolytes, on the other hand, YSZ-HT showed the highest sintering rate with a dense microstructure at a co-sintering temperature of 1250 °C. Our results indicate that besides the average particle size, other factors such as particle size distribution and post-processing play a significant role in determining the sintering rate and densification behavior of the YSZ powders. Additionally, a close match in the sintering shrinkage of the electrolyte and anode support is important for facilitating the densification of the thin-film electrolytes.

As the primary greenhouse gas, CO₂ emission has noticeably increased over the past decades resulting in global warming and climate change. Surprisingly, anthropogenic activities have increased atmospheric CO₂ by 50% in less than 200 years, causing more frequent and severe rainfall, snowstorms, flash floods, droughts, heat waves, and rising sea levels in recent times. Hence, reducing the excess CO₂ in the atmosphere is imperative to keep the global average temperature rise below 2 °C. Among many CO₂ mitigation approaches, CO₂ capture using porous materials is considered one of the most promising technologies. Porous solid materials such as carbons, silica, zeolites, hollow fibers, and alumina have been widely investigated in CO₂ capture technologies. Interestingly, porous silica-based materials have recently emerged as excellent candidates for CO₂ capture technologies due to their unique properties, including high surface area, pore volume, easy surface functionalization, excellent thermal, and mechanical stability, and low cost. Therefore, this review comprehensively covers major CO₂ capture processes and their pros and cons, selecting a suitable sorbent, use of liquid amines, and highlights the recent progress of various porous silica materials, including amine-functionalized silica, their reaction mechanisms and synthesis processes. Moreover, CO₂ adsorption capacities, gas selectivity, reusability, current challenges, and future directions of porous silica materials have also been discussed.

Solid Oxide Cells (SOC) are the kind of electrochemical devices that provide reversible, dual mode operation, where electricity is generated in a fuel cell mode and fuel is produced in an electrolysis mode. Our current work encompasses the design, fabrication, and performance analysis of a micro-tubular reversible SOC that is prepared through a single dip-coating technique with multiple dips using conventional materials. Electrochemical impedance and current-voltage responses were monitored from 700 to 800 °C. Maximum power densities of the cell achieved at 800, 750, and 700 °C, was 690, 546, and 418 mW cm⁻², respectively. The reversible, dual mode operation of the SOC was evaluated by operating the cell using 50% H₂O/H₂ and ambient air. Accordingly, when the SOC was operated in the electrolysis mode at 1.3 V (the thermo-neutral voltage for steam electrolysis), current densities of −311, −487 and −684 mA cm⁻² at 700, 750 and 800 °C, respectively, were observed. Hydrogen production rate was determined based on the current developed in the cell during the electrolysis operation. The stability of the cell was further evaluated by performing multiple transitions between fuel cell mode and electrolysis mode at 700 °C for a period of 500 h. In the stability test, the cell current decreased from 353 mA cm⁻² to 243 mA cm⁻² in the fuel cell mode operation at 0.7 V, while the same decreased from −250 mA cm⁻² to −115 mA cm⁻² in the electrolysis operation at 1.3 V.