A LaFeO₃ photocatalyst is obtained by solution combustion synthesis from a bio-based substance extracted from urban wastes and tested for its catalytic activity.

The growing utilization of renewable and residual biomasses for environmental preservation and remediation are important goals to be pursued to minimize the environmental impact of human activities. In this paper, sodium alginate (derived from brown algae) was crosslinked using chitosan (mainly derived from the exoskeleton of crustaceans) in the presence of biowaste-derived substances isolated from green compost (BBS-GC), to produce hydrogels and dried films. The obtained materials were tested as adsorbents for wastewater remediation. To this purpose, gels were characterized using a multi-analytical approach and used as active substrates for the removal of three differently-charged molecules, chosen as model pollutants: crystal violet, rhodamine B, and orange II. The effectiveness of the gel formulations was demonstrated and attributed to the variety of active functionalities introduced by the different precursors, the structural factors and the peculiar physicochemical properties of the resulting materials.

Today, the theme of environmental preservation plays an important role within the activities of the scientific community and influences the choices of politics and the common population. In this context, the use of non-fossil substances should be promoted for different reasons: to avoid the depletion and damage of the areas involved in the fossil fuel extraction, decrease the impact of emissions/by-products related to the industrial transformation of fossil-based products and possibly exploit residual biomasses as sources of carbon. This latter aspect also can be viewed as a way to revalorize lignocellulose waste, generally destined to dump as putrescible matter or to be incinerated. In this review, we are aiming to present a concise overview of the multiple functions of lignocellulose biomass in the broad field of catalysis for a sustainable development. The originality of the approach is considering the lignocellulose-derived matter in three different aspects: (i) as a precursor to convert into platform molecules, (ii) as an active material (i.e., humic-like substances as photosensitizers) and (iii) as a green support for catalytic applications. We find that this perspective can widen the awareness level of scientists involved in the catalysis field for the exploitation of residual biomass as a valuable and complementary resource.

Soybean hulls (SBHs) are one of the main by-products of soybean crushing, usually destined for animal feeding or to become a putrescible waste. In this work, we upgraded the SBHs to materials with antimicrobial properties. After the extraction of soybean peroxidase from SBHs, an enzyme applicable in different technological sectors and naturally present in soybean hulls, the exhausted biomass was subjected to an acid–base treatment to isolate cellulose. The obtained material was, in turn, functionalized with 3-aminopropyl triethoxysilane (APTES) to achieve new hybrids with antimicrobial properties. The synthetic procedure was optimized by varying the solvent type (ethanol or toluene) and APTES amount. Overall, the amino-functionalization process was effective and the activity was outstanding against both gram-positive and gram-negative bacteria, reaching complete disinfection practically in all cases. The samples were studied by means of several characterization techniques, demonstrating that the solvent and cellulose types had a significant influence on the physical–chemical features, together with the eco-sustainability of the process. In particular, the use of greener ethanol and waste cellulose (with respect to a commercial one) resulted in a higher APTES immobilization efficiency and superior thermal stability of the final materials. Interestingly, the presence of various unremoved compounds from the lignocellulosic SBH matrix, although in small quantities, emerged as a crucial factor, also in terms of antibacterial activity, hypothesizing a role of residual phytochemicals.