This work gives an insight into the transient softening at the fusion boundary of resistance spot welds on hot stamped steel. Metallographic investigations and hardness mapping were combined with finite phase–field modeling of phase evolution at the fusion boundary. Saturation of weld nugget growth in the welding process was observed. For industrially relevant, long welding times, the fusion boundary of a spot weld is therefore isothermally soaked between the peritectic and solidus temperatures. This leads to a carbon segregation to the liquid phase due to higher carbon solubility and possibly to δ-Fe formation at the fusion boundary. Both results in a local carbon depletion at the fusion boundary. This finding is in good agreement with carbon content measurements at the fusion boundary and the results of hardness measurements.