Novel fibrous graphitic carbon nitride (g-C₃N₄) derivatives prepared from metal organic frameworks (MOFs) were doped with Ce³⁺ (Ce-C₃N₄) as photocatalytic materials. Ce-C₃N₄ was characterized using various techniques, revealing its high specific surface area, excellent photocatalytic activity, and stability for H₂ evolution under visible light irradiation. The fluorine modified samples show superior photocatalytic activity under visible light irradiation, which is due to the presence of more active sites and enhanced absorption of solar energy. This work provides a new synthetic route for MOF-derived g-C₃N₄ that can be doped with different metal ions. The fluorine modified Ce-C₃N₄ is an efficient photocatalyst with potential for many applications related to energy and the environment.